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45707

Zineb

Name: Zineb
Brand: SIAL

PESTANAL^®, analytical standard

Synonym(s):

Zinc-ethylenebis(dithiocarbamate)

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About This Item

Empirical Formula (Hill Notation):

C₄H₆N₂S₄Zn

CAS Number:

12122-67-7

Molecular Weight:

275.75

UNSPSC Code:

41116107

NACRES:

NA.24

PubChem Substance ID:

329756916

EC Number:

235-180-1

Beilstein/REAXYS Number:

4165797

MDL number:

MFCD00067266

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grade

analytical standard

Quality Level

100

description

technical mixture

product line

PESTANAL^®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

S=C1NCCNC(=S)S[Zn]S1

InChI

1S/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2

InChI key

AMHNZOICSMBGDH-UHFFFAOYSA-L

Related Categories

Analytical Chemistry

Pesticide Standards

Reference Materials

General description

Zineb belongs to the ethylenebisdithiocarbamates (EBDCs) class of compounds which has been employed in crop protection.

Application

Zineb may be used as the reference standard for the determination of zineb in wheat samples by capillary electrophoresis with ultraviolet (UV) detection, in commercial formulations by flow injection analysis-atomic absorption spectrometry (FIA-AAS), environmental water samples by liquid chromatography-mass spectrometry (LC-MS) in scanning or selected ion monitoring (SIM) mode and in synthetic samples, spiked water samples and crops by H-point standard addition method (HPSAM) combined with ultraviolet-visible (UV-Vis) spectrophotometry.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

GHS07,GHS09

signalword

Warning

hcodes

H302,H317,H335,H410

pcodes

P261 - P264 - P273 - P280 - P301 + P312 - P302 + P352

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Information

农药列管产品

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Certificates of Analysis (COA)

Lot/Batch Number

BCCH9799

BCBW7432

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Ship hull in-water cleaning and its effects on fouling-control coatings.

Dinis Reis Oliveira et al.

Biofouling, 36(3), 332-350 (2020-05-14)

Today, ship hull fouling is managed through fouling-control coatings, complemented with in-water cleaning. During cleaning, coating damage and wear must be avoided, for maximum coating lifetime and reduced antifoulant release. When possible, cleaning should target early stages of fouling, using

LC/MS studies on characterization and determination of N,N′-ethylenebisdithiocarbamate fungicides in environmental water samples.

Hanada Y, et al.

Analytical Sciences, 18(4), 441-444 (2002)

Capillary electrophoretic determination of zinc dimethyldithiocarbamate (Ziram) and zinc ethylenebisdithiocarbamate (Zineb).

Malik AK and Faubel W

Talanta, 52(2), 341-346 (2000)

Flow injection/atomic absorption spectrometric determination of zineb in commercial formulations of pesticide based on slurry sampling.

Cassella RJ, et al.

Analytical Sciences, 18(11), 1253-1256 (2002)

H-Point standard addition method for simultaneous determination of maneb and zineb.

Kaur PP and Gupta U

Journal of Chemistry, 6(1), 106-112 (2009)

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Global Trade Item Number

SKU	GTIN
45707-250MG	04061834044536

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