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Merck
CN

45707

Zineb

PESTANAL®, analytical standard

Synonym(s):

Zinc-ethylenebis(dithiocarbamate)

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About This Item

Empirical Formula (Hill Notation):
C4H6N2S4Zn
CAS Number:
12122-67-7
Molecular Weight:
275.75
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329756916
EC Number:
235-180-1
Beilstein/REAXYS Number:
4165797
MDL number:
MFCD00067266

Key Documents

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Product Name

Zineb, PESTANAL®, analytical standard

InChI key

AMHNZOICSMBGDH-UHFFFAOYSA-L

InChI

1S/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2

SMILES string

S=C1NCCNC(=S)S[Zn]S1

grade

analytical standard

description

technical mixture

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Zineb may be used as the reference standard for the determination of zineb in wheat samples by capillary electrophoresis with ultraviolet (UV) detection, in commercial formulations by flow injection analysis-atomic absorption spectrometry (FIA-AAS), environmental water samples by liquid chromatography-mass spectrometry (LC-MS) in scanning or selected ion monitoring (SIM) mode and in synthetic samples, spiked water samples and crops by H-point standard addition method (HPSAM) combined with ultraviolet-visible (UV-Vis) spectrophotometry.

General description

Zineb belongs to the ethylenebisdithiocarbamates (EBDCs) class of compounds which has been employed in crop protection.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCH9799
BCBW7432

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LC/MS studies on characterization and determination of N,N′-ethylenebisdithiocarbamate fungicides in environmental water samples.
Hanada Y, et al.
Analytical Sciences, 18(4), 441-444 (2002)
Dinis Reis Oliveira et al.
Biofouling, 36(3), 332-350 (2020-05-14)
Today, ship hull fouling is managed through fouling-control coatings, complemented with in-water cleaning. During cleaning, coating damage and wear must be avoided, for maximum coating lifetime and reduced antifoulant release. When possible, cleaning should target early stages of fouling, using
Capillary electrophoretic determination of zinc dimethyldithiocarbamate (Ziram) and zinc ethylenebisdithiocarbamate (Zineb).
Malik AK and Faubel W
Talanta, 52(2), 341-346 (2000)
H-Point standard addition method for simultaneous determination of maneb and zineb.
Kaur PP and Gupta U
Journal of Chemistry, 6(1), 106-112 (2009)
Flow injection/atomic absorption spectrometric determination of zineb in commercial formulations of pesticide based on slurry sampling.
Cassella RJ, et al.
Analytical Sciences, 18(11), 1253-1256 (2002)
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