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Merck
CN

45751

Diflufenican

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C19H11F5N2O2
CAS Number:
83164-33-4
Molecular Weight:
394.29
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329756934
MDL number:
MFCD01311804
Beilstein/REAXYS Number:
4212494

Key Documents

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InChI key

WYEHFWKAOXOVJD-UHFFFAOYSA-N

SMILES string

Fc1ccc(NC(=O)c2cccnc2Oc3cccc(c3)C(F)(F)F)c(F)c1

InChI

1S/C19H11F5N2O2/c20-12-6-7-16(15(21)10-12)26-17(27)14-5-2-8-25-18(14)28-13-4-1-3-11(9-13)19(22,23)24/h1-10H,(H,26,27)

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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General description

Diflufenican is a pre- and early post-emergence herbicide used to control dicotyledonous weeds in winter cereals, including Galium aparine, Veronica hederifolia, Veronica persica and Viola arvensis, which are resistant to substituted urea herbicides.

Application

Diflufenican may be used as a reference standard in the determination of diflufenican in water samples using solid-phase microextraction followed by gas chromatography coupled with ion trap-tandem mass spectrometry (SPME-GC-ITD-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0244
BCCG3122
BCBT7190

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Analytical methods for the determination of isoproturon and diflufenican residues in runoff and soil.
L Patty et al.
Bulletin of environmental contamination and toxicology, 55(6), 802-809 (1995-12-01)
Design and synthesis of N-(2, 4= difluorophenyl)-2-(3-trifluoromethylphenoxy)-3-pyridinecarboxamide (diflufenican), a novel pre-and early post-emergence herbicide for use in winter cereals.
Cramp CM, et al
Pestic. Sci., 18(1), 15-28 (1987)
Zhanli Hu et al.
Journal of the science of food and agriculture, 101(1), 215-219 (2020-07-06)
In order to clarify whether the application of diflufenican in the wheat field will produce residues in wheat plants and soil. In this experiment, ultra-high-pressure liquid chromatography was used to determine the residues of diflufenican in wheat plants, grains, and
Huan Lu et al.
Pest management science, 76(6), 2015-2020 (2019-12-24)
Diflufenican resistance has been reported in wild radish populations since 1998, but the resistance mechanisms have not been investigated. Recently, we identified a wild radish population (H2/10) from the Western Australian grain belt that is resistant (R) to the phytoene
Gabriel S Weyman et al.
Environmental toxicology and chemistry, 31(7), 1662-1669 (2012-05-01)
Aquatic toxicity tests with substances that are poorly soluble in water have been conducted using different methods, and estimates of toxicity have varied accordingly. The present study illustrates differences in toxicity values resulting from variation in test designs and solution
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