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Merck
CN

51949

Azoxystrobin-(cyanophenoxy-d4)

analytical standard, PESTANAL®

Synonym(s):

Azoxystrobin-d4

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About This Item

Empirical Formula (Hill Notation):
C22D4H13N3O5
Molecular Weight:
407.41
MDL number:
UNSPSC Code:
77101502
NACRES:
NA.24
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grade

analytical standard

Quality Segment

product line

PESTANAL®

assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture

format

neat

storage temp.

2-8°C

SMILES string

O=C(OC)/C(C1=C(OC2=NC=NC(OC3=C(C#N)C([2H])=C([2H])C([2H])=C3[2H])=C2)C=CC=C1)=C/OC

InChI

1S/C22H17N3O5/c1-27-13-17(22(26)28-2)16-8-4-6-10-19(16)30-21-11-20(24-14-25-21)29-18-9-5-3-7-15(18)12-23/h3-11,13-14H,1-2H3/b17-13+/i3D,5D,7D,9D

InChI key

WFDXOXNFNRHQEC-IRBJAXQRSA-N

General description

Azoxystrobin-(cyanophenoxy-d4) is an isotope-labeled analog of azoxystrobin, a systemic fungicide of the strobilurin group, widely used for the control of Plasmopara Viticola and Uncinula in grapes, grey mold in a variety of crops, including vegetables, ornamentals and strawberries.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

Skull and crossbonesEnvironment

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable



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