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Merck
CN

56816

Clothianidin-d3

PESTANAL®, analytical standard

Synonym(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-(methyl-d3)-2-nitroguanidine

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About This Item

Empirical Formula (Hill Notation):
C6D3H5ClN5O2S
CAS Number:
Molecular Weight:
252.70
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
MDL number:
Technical Service
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grade

analytical standard

Quality Level

product line

PESTANAL®

assay

≥97.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

mass shift

M+3

SMILES string

[2H]C([2H])([2H])N\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)/i1D3

InChI key

PGOOBECODWQEAB-FIBGUPNXSA-N

General description

Find more information here: Neonicotinoids

Application

Clothianidin-d3 may be used as a standard for the determination of neonicotinoid in milk by ultrahigh performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Certificates of Analysis (COA)

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Protocols

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.


Timothy A Bargar et al.
PeerJ, 8, e8669-e8669 (2020-03-21)
Recent concern for the adverse effects from neonicotinoid insecticides has centered on risk for insect pollinators in general and bees specifically. However, natural resource managers are also concerned about the risk of neonicotinoids to conservation efforts for the monarch butterfly
Daniel B Pickford et al.
Environmental toxicology and chemistry, 37(4), 1040-1050 (2017-11-07)
Thiamethoxam is a widely used neonicotinoid insecticide that has been detected in surface water monitoring programs in North America and Europe. This has led to questions about its toxicity to nontarget insects, specifically those with an aquatic life stage. To
Development and Validation of an Ultra-Sensitive UHPLC-MS/MS Method for Neonicotinoid Analysis in Milk.
Lachat L and Glauser G
Journal of Agricultural and Food Chemistry, 66(32), 8639-8646 (2018)



Global Trade Item Number

SKUGTIN
56816-50MG04061832589701