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Merck
CN

63380

Dimethyl malonate

purum, ≥96.0% (GC)

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About This Item

Linear Formula:
CH2(COOCH3)2
CAS Number:
108-59-8
Molecular Weight:
132.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
329759847
EC Number:
203-597-8
Beilstein/REAXYS Number:
774261
MDL number:
MFCD00008460
Assay:
≥96.0% (GC)

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Product Name

Dimethyl malonate, purum, ≥96.0% (GC)

InChI key

BEPAFCGSDWSTEL-UHFFFAOYSA-N

InChI

1S/C5H8O4/c1-8-4(6)3-5(7)9-2/h3H2,1-2H3

SMILES string

COC(=O)CC(=O)OC

vapor density

>1 (vs air)

grade

purum

assay

≥96.0% (GC)

refractive index

n20/D 1.413 (lit.)
n20/D 1.413

bp

180-181 °C (lit.)

mp

−62 °C (lit.)

density

1.156 g/mL at 25 °C (lit.)

functional group

ester

Quality Level

100

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pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD4076
BCCB4125
BCCB1357
BCBW2735
BCBP2622V

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M Coker et al.
Journal of inherited metabolic disease, 19(6), 743-751 (1996-01-01)
Total plasma odd-numbered long-chain fatty acids were analysed in patients with methylmalonic acidaemia (vitamin B12-responsive and unresponsive), combined methylmalonic acidaemia/homocystinuria (CblC), propionic acidaemia (both neonatal-onset and late-onset), biotinidase deficiency and holocarboxylase synthase deficiency, as well as in hospital controls. Total
Lawrence P Tardibono et al.
Organic letters, 11(18), 4076-4079 (2009-08-22)
Homoallylic esters are obtained in a single transformation from allyl 2,2,2-trifluoroethyl malonates by using a Pd(0) catalyst. Facile decarboxylation of allyl 2,2,2-trifluoroethyl malonates is attributed to a decrease in pK(a) compared to allyl methyl malonates. Subsequent reduction of the homoallylic
K Hiroi et al.
Chemical & pharmaceutical bulletin, 48(3), 405-409 (2000-03-22)
The Lewis acid-mediated reactions of allene-ene compounds, derived from 3-methylcitronellal or dimethyl malonate, were carried out using various Lewis acids such as ethylaluminum dichloride, diethylaluminum chloride, titanium chloride, zinc chloride etherate, or boron trifluoride etherate, affording unexpectedly intramolecular [2+2]cycloaddition products
Shinji Kato
Journal of the American Chemical Society, 127(33), 11538-11539 (2005-08-18)
Layer-by-layer (LbL) assembly of triarylamine (TAA)-containing polymers has been applied for anode functionalizations in organic light-emitting diodes (OLEDs). Surface work function of the ITO electrodes was significantly altered with the functionalizations, and the values changed depending on electron affinity of
A Martínez Bermejo et al.
Revista de neurologia, 33(2), 101-111 (2001-09-20)
The presence in neuroimaging of areas of symmetrical bilateral hypodensity in the basal ganglia (SBHBG) is a striking and unusual finding. To determine the aetiology, clinical significance and evolution of a group of paediatric patients with SBHBG. We made a
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