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Merck
CN

63380

Dimethyl malonate

purum, ≥96.0% (GC)

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About This Item

Linear Formula:
CH2(COOCH3)2
CAS Number:
Molecular Weight:
132.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-597-8
Beilstein/REAXYS Number:
774261
MDL number:
Assay:
≥96.0% (GC)
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vapor density

>1 (vs air)

Quality Level

grade

purum

assay

≥96.0% (GC)

refractive index

n20/D 1.413

bp

180-181 °C (lit.)

mp

−62 °C (lit.)

density

1.156 g/mL at 25 °C (lit.)

functional group

ester

SMILES string

COC(=O)CC(=O)OC

InChI

1S/C5H8O4/c1-8-4(6)3-5(7)9-2/h3H2,1-2H3

InChI key

BEPAFCGSDWSTEL-UHFFFAOYSA-N



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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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Lawrence P Tardibono et al.
Organic letters, 11(18), 4076-4079 (2009-08-22)
Homoallylic esters are obtained in a single transformation from allyl 2,2,2-trifluoroethyl malonates by using a Pd(0) catalyst. Facile decarboxylation of allyl 2,2,2-trifluoroethyl malonates is attributed to a decrease in pK(a) compared to allyl methyl malonates. Subsequent reduction of the homoallylic
Shinji Kato
Journal of the American Chemical Society, 127(33), 11538-11539 (2005-08-18)
Layer-by-layer (LbL) assembly of triarylamine (TAA)-containing polymers has been applied for anode functionalizations in organic light-emitting diodes (OLEDs). Surface work function of the ITO electrodes was significantly altered with the functionalizations, and the values changed depending on electron affinity of
DNA-based catalytic enantioselective michael reactions in water.
David Coquière et al.
Angewandte Chemie (International ed. in English), 46(48), 9308-9311 (2007-10-31)



Global Trade Item Number

SKUGTIN
63380-250ML04061832721705
63380-1L04061836693008