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Merck
CN

67575

4-Chlorobenzyl chloride

analytical standard

Synonym(s):

α,4-Dichlorotoluene, (4-Chlorophenyl)methyl chloride, 1-Chloro-4-(chloromethyl)benzene, NSC 34032

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About This Item

Linear Formula:
ClC6H4CH2Cl
CAS Number:
104-83-6
Molecular Weight:
161.03
UNSPSC Code:
77101502
NACRES:
NA.24
PubChem Substance ID:
329760621
EC Number:
203-242-7
Beilstein/REAXYS Number:
471558
MDL number:
MFCD00000914

Key Documents

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Product Name

4-Chlorobenzyl chloride, analytical standard

InChI key

JQZAEUFPPSRDOP-UHFFFAOYSA-N

InChI

1S/C7H6Cl2/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2

SMILES string

ClCc1ccc(Cl)cc1

grade

analytical standard

assay

≥97.0% (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

216-222 °C (lit.)

mp

27-29 °C (lit.)

application(s)

environmental
pharmaceutical

format

neat

Quality Level

100

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General description

4-Chlorobenzyl chloride is generally used in the preparation of quaternary ammonium salts. It acts as an intermediate in the production of rice herbicide, pharmaceuticals and pesticides.

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

flash_point_f

226.4 °F - closed cup

flash_point_c

108 °C - closed cup

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCH1725
BCCC6221
BCBV9777

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A catalytic method for the selective chlorination of benzyl chloride to 4-chlorobenzyl chloride using zeolite catalysts
Kale SM and Singh AP
J. Mol. Catal. A: Chem., 138(2-3), 263-272 (1999)

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