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86893

Tetrabutylammonium perchlorate

Name: Tetrabutylammonium perchlorate
Brand: SIAL

for electrochemical analysis, ≥99.0%

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About This Item

Linear Formula:

(CH₃CH₂CH₂CH₂)₄N(ClO₄)

CAS Number:

1923-70-2

Molecular Weight:

341.91

UNSPSC Code:

26111700

NACRES:

NB.61

PubChem Substance ID:

329769341

EC Number:

217-655-5

Beilstein/REAXYS Number:

3579274

MDL number:

MFCD00038722

Assay:

≥99.0% (T), ≥99.0%

Form:

powder

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Quality Level

100

assay

≥99.0% (T), ≥99.0%

form

powder

mp

211-215 °C

solubility

acetonitrile: 0.1 g/mL, clear, colorless

SMILES string

[O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

KBLZDCFTQSIIOH-UHFFFAOYSA-M

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Related Categories

Analytical Chemistry

Analytical Reagents

Chromatography & Spectroscopy Reagents

General description

Tetrabutylammonium perchlorate (TBAP) is a quaternary ammonium salt, mainly used as electrolyte.

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Application

TBAP has been used as solvent in preparing standard stock solutions, for HPLC analysis of Sudan azo-dyes food samples. It may be used as an electrophoretic buffer to rinse the capillary for the nonaqueous capillary electrophoresis (NACE) determination of atropine, anisodamine, and scopolamine in Flos daturae plant extract.

pictograms

GHS03,GHS07

signalword

Danger

hcodes

H272,H315,H319,H335

pcodes

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection.

Yuan B

Journal of Chromatography A, 1217(1), 171-174 (2010)

Analysis of sudan I, sudan II, sudan III, and sudan IV in food by HPLC with electrochemical detection: Comparison of glassy carbon electrode with carbon nanotube-ionic liquid gel modified electrode.

Chailapakul O

Food Chemistry, 109(4), 876-882 (2008)

Molecular recognition in Mn-catalyzed C-H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective.

David Balcells et al.

Dalton transactions (Cambridge, England : 2003), (30)(30), 5989-6000 (2009-07-23)

Experimental studies have shown that the C-H oxidation of Ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivities using [(terpy')Mn(OH(2))(mu-O)(2)Mn(OH(2))(terpy')](3+) as catalyst, where terpy' is a terpyridine ligand functionalized with a phenylene linker and a Kemp's triacid

Polarized near-infrared intersubband absorptions in CdSe colloidal quantum wells.

Benjamin T Diroll et al.

Nature communications, 10(1), 4511-4511 (2019-10-06)

Colloidal quantum wells are two-dimensional materials grown with atomically-precise thickness that dictates their electronic structure. Although intersubband absorption in epitaxial quantum wells is well-known, analogous observations in non-epitaxial two-dimensional materials are sparse. Here we show that CdSe nanoplatelet quantum wells

Breaking aggregation in a tetrathiafulvalene-fused zinc porphyrin by metal-ligand coordination to form a donor-acceptor hybrid for ultrafast charge separation and charge stabilization.

Atanu Jana et al.

Dalton transactions (Cambridge, England : 2003), 44(1), 359-367 (2014-11-11)

A novel electron rich, tetrathiafulvalene fused zinc porphyrin, (TTF)4PZn, has been newly synthesized and characterized using spectral and electrochemical methods. In spite of the presence of eight t-butyl groups, (TTF)4PZn exhibited appreciable aggregation in solution. Scanning electron microscopic (SEM) imaging

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Global Trade Item Number

SKU	GTIN
86893-50G	04061833042113
86893-10G	04061833042106

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