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Merck
CN

86899

Tetrabutylammonium phosphate monobasic solution

suitable for ion pair chromatography, LiChropur™, concentrate, ampule

Synonym(s):

Tetrabutylammonium dihydrogen phosphate

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS Number:
5574-97-0
Molecular Weight:
339.45
UNSPSC Code:
23151817
NACRES:
NB.21
PubChem Substance ID:
329769345
MDL number:
MFCD00064526
Beilstein/REAXYS Number:
5196532

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InChI

1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1

SMILES string

OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI key

ARRNBPCNZJXHRJ-UHFFFAOYSA-M

description

cationic

form

liquid

quality

LiChropur™, ampule

packaging

ampule of 25 mL

technique(s)

ion pair chromatography: suitable

λ

in concentrate

UV absorption

λ: 210 nm Amax: 0.05, λ: 220 nm Amax: 0.04, λ: 300 nm Amax: 0.02, λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test, corresponds to standard for filter test

storage temp.

2-8°C

Quality Level

100

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General description

Concentrate for 6x1 L ready-to-use solution. Dilute contents of one ampule (~0.3 M) to 1 L with HPLC grade water to obtain a 0.005 M eluent solution.
Tetrabutylammonium dihydrogen phosphate is a quaternary ammonium salt mainly used as electrolyte.

Application

Tetrabutylammonium dihydrogen phosphate has been used as ion-pairing reagent in mobile phase for ion-pair HPLC analysis of 5′-mononucleotides from baby formulae. It may also have been used in mobile phase for HPLC analysis of blood samples to determine acetaminophen.

Other Notes

Ion-pairing reagent used in reversed phase chromatography

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Storage Class

10 - Combustible liquids

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCBS3504V
BCCC2094
BCBR6388V
BCBR6288V
BCBQ7540V

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K Makino et al.
Journal of chromatography, 400, 271-277 (1987-07-29)
The separation of large oligodeoxyribonucleotides, synthesized chemically and subsequently deblocked, was carried out by reversed-phase ion-pair chromatography (RP-IPC) with a linear gradient of acetonitrile concentration. It was found that tetrabutylammonium phosphate is suitable as an ion-pairing reagent and produces a
C.F. Harrington et al.
Journal of Liquid Chromatography and Related Technologies, 20, 1773-1773 (1997)
The analysis of 5'-mononucleotides in infant formulae by HPLC.
Perrin, Christian, et al.
Food Chemistry, 74.2, 245-253 (2001)
In situ gelling and mucoadhesive liquid suppository containing acetaminophen: enhanced bioavailability.
Choi, Han-Gon, Yu-Kyoung Oh, and Chong-Kook Kim.
International Journal of Pharmaceutics, 165.1, 23-32 (1998)
W.E. Ladner et al.
The Journal of Organic Chemistry, 50, 1076-1076 (1985)
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