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Merck
CN

90179

Morpholine

analytical standard

Synonym(s):

Tetrahydro-1,4-oxazine

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About This Item

Empirical Formula (Hill Notation):
C4H9NO
CAS Number:
Molecular Weight:
87.12
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
203-815-1
Beilstein/REAXYS Number:
102549
MDL number:
Technical Service
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grade

analytical standard

Quality Level

vapor density

3 (vs air)

vapor pressure

31 mmHg ( 38 °C), 7 mmHg ( 20 °C)

assay

≥99.5% (GC)

autoignition temp.

590 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

10.8 %

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.454 (lit.), n20/D 1.455

bp

129 °C (lit.)

mp

−7-−5 °C (lit.)

density

1.000 g/mL at 20 °C, 0.996 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

C1COCCN1

InChI

1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2

InChI key

YNAVUWVOSKDBBP-UHFFFAOYSA-N

General description

Morpholines are systemic compounds that exert both protective and curative actions against fungal diseases.

Application

Morpholine has been used as a reference standard for the identification of the analyte in water by gas chromatography-mass spectrometry (GC-MS). It may be used as a reference standard for the determination of the analyte in fruit-based soft drinks, in natural waters and in vegetables by liquid chromatography-mass spectrometry (LC-MS) and in drugs by GC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

87.8 °F - closed cup

flash_point_c

31 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Development of a Method for Rapid Determination of Morpholine in Juices and Drugs by Gas Chromatography-Mass Spectrometry
Cao M, et al.
Journal of Analytical Methods in Chemistry, 2018(2), 161-169 (2018)
Metabolic pathways of agrochemicals: insecticides and fungicides
Metabolic Pathways of Agrochemicals: Herbicides and Plant Growth Regulators, 1 (1998)
Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables.
Sannino A, et al.
Journal of Chromatography A, 1036(2), 161-169 (2004)



Global Trade Item Number

SKUGTIN
90179-5ML-F04061836959371
90179-10ML-F04061833246436