908800
Chiralyst Rh660
Umicore, powder
Synonym(s):
1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, (R,R)-Et-DUPHOS-Rh, [(R,R)Ethyl-DuPhosRh(COD)]BF4
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About This Item
Empirical Formula (Hill Notation):
C30H48BF4P2Rh
CAS Number:
Molecular Weight:
660.36
UNSPSC Code:
12352005
NACRES:
NA.22
Product Name
Chiralyst Rh660, Umicore
form
powder
SMILES string
C[CH+]C.CC[C@@H]1CC[C@@H](CC)P12C3=C(P4([Rh](C)2C)[C@H](CC)CC[C@H]4CC)C=CC=C3.FB(F)F.C5C/C=C\CC/C=C\5.[F-]
InChI
1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m1.../s1
InChI key
DSYBEQKPSKLNMC-KYOOHHHUSA-N
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
Catalyst for:
- Asymmetric hydrogenation reactions
Chiralyst Rh660 is a homogeneous catalyst useful for asymmetric reactions and asymmetric hydrogenation.
The catalyst works well with privileged ligands.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
The catalyst works well with privileged ligands.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Preparation Note
Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
Legal Information
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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