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93092

Triphenylphosphine

Name: Triphenylphosphine
Brand: SIAL

≥95.0% (GC), crystals

Synonym(s):

Phosphorustriphenyl

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About This Item

Linear Formula:

(C₆H₅)₃P

CAS Number:

603-35-0

Molecular Weight:

262.29

NACRES:

NA.21

PubChem Substance ID:

57653514

UNSPSC Code:

12352100

EC Number:

210-036-0

MDL number:

MFCD00003043

Beilstein/REAXYS Number:

610776

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Properties

Product Name

Triphenylphosphine, ≥95.0% (GC)

Quality Segment

200

vapor density

9 (vs air)

vapor pressure

5 mmHg ( 20 °C)

assay

≥95.0% (GC)

form

crystals

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

impurities

~3% triphenylphosphine oxide

bp

377 °C (lit.)

mp

77-84 °C, 79-81 °C (lit.)

solubility

water: soluble 0.00017 g/L at 22 °C

functional group

phosphine

SMILES string

c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

RIOQSEWOXXDEQQ-UHFFFAOYSA-N

Description

General description

Triphenylphosphine, also referred to as PPH₃, is an organophosphorous compound. It readily forms complexes with platinum-metal group salts.

Application

The palladium-based complexes bearing 1, 3-dibenzylbenzimidazolium with morpholine, triphenylphosphine, and pyridine derivate ligands: This study discusses the synthesis and characterization of new palladium-based complexes incorporating triphenylphosphine, providing insights into their potential catalytic activities (Aktaş et al., 2022).

Polymer-supported triphenylphosphine: This review highlights the diverse applications of polymer-supported triphenylphosphine in organic synthesis and its significant role in promoting more sustainable and efficient chemical processes (Moussa et al., 2019).

Application prospects of triphenylphosphine-based mitochondria-targeted cancer therapy: The review focuses on the utilization of triphenylphosphine for developing mitochondria-targeted drugs, emphasizing its potential in cancer therapy (Cheng et al., 2023).

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signalword

Danger

target_organs

Central nervous system,Peripheral nervous system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

356.0 °F - closed cup

flash_point_c

180 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Hazard Classifications

Acute Tox. 4 Oral - Skin Sens. 1B - STOT RE 1 Inhalation

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