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2,4,6-Tris(2-pyridyl)-s-triazine

for spectrophotometric det. of Fe, ≥99.0% (HPLC)

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Synonym(s):
2,4,6-Tri(2-pyridyl)-s-triazine, TPTZ
Empirical Formula (Hill Notation):
C18H12N6
CAS Number:
Molecular Weight:
312.33
Beilstein:
282581
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

Quality Level

Assay

≥99.0% (HPLC)

form

lumps

quality

for spectrophotometric det. of Fe

technique(s)

UV/Vis spectroscopy: suitable

loss

≤0.1 wt. % loss on drying

mp

247-249 °C (lit.)
248-252 °C

solubility

methanol: 100 mg/mL, clear to slightly hazy

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤100 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES string

c1ccc(nc1)-c2nc(nc(n2)-c3ccccn3)-c4ccccn4

InChI

1S/C18H12N6/c1-4-10-19-13(7-1)16-22-17(14-8-2-5-11-20-14)24-18(23-16)15-9-3-6-12-21-15/h1-12H

InChI key

KMVWNDHKTPHDMT-UHFFFAOYSA-N

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General description

2,4,6-Tris(2-pyridyl)-s-triazine is a Case and Koft compound generally used in determination of iron in a colorimetric analysis.

Other Notes

Reagent for the spectrophotometric determination of Fe(II) and of total Fe

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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2, 4, 6-Tripyridyl-s-triazine as reagent for iron. Determination of iron in limestone, silicates, and refractories.
Collins, Peter F., Harvey Diehl, and G. Frederick Smith.
Analytical Chemistry, 31.11, 1862-1867 (1959)
J. Flock et al.
Fresenius Journal of Analytical Chemistry, 346, 667-667 (1993)
P.F. Collins et al.
Analytical Chemistry, 31, 1862-1862 (1959)
D Ben-Shachar et al.
Journal of neurochemistry, 45(4), 999-1005 (1985-10-01)
Nutritional iron deficiency induced in rats causes a selective reduction of [3H]spiperone binding in caudate nucleus. This effect can be reversed by iron supplementation in vivo. The possibility that iron may be involved in the dopamine D2 receptor was investigated
Atomic-absorption spectrometric determination of copper(I) after adsorption of its 2,4,6-tri(2-pyridyl)-1,3,5-triazine complex with tetraphenylborate anion on microcrystalline naphthalene.
J L Lin et al.
The Analyst, 110(11), 1351-1354 (1985-11-01)

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