Skip to Content
Merck
CN

Key Documents

View All Documentation

95447

Bis[tris(4-(1H,1H,2H,2H-perfluorodecyl)phenyl)phosphine]palladium(II) dichloride

technical, ≥80% (AAS)

Synonym(s):

Bis[tris(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)phenyl)phosphine]palladium(II) dichloride

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C96H48Cl2F102P2Pd
CAS Number:
326475-46-1
Molecular Weight:
3378.52
NACRES:
NA.21
PubChem Substance ID:
329770462
UNSPSC Code:
12161600
MDL number:
MFCD03453279
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

grade

technical

Quality Level

100

assay

≥80% (AAS)

form

powder

reaction suitability

reagent type: catalyst
core: palladium

mp

175-180 °C

SMILES string

Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc1ccc(cc1)P(c2ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc2)c3ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc3.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc4ccc(cc4)P(c5ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc5)c6ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc6

InChI

1S/2C48H24F51P.2ClH.Pd/c2*49-25(50,28(55,56)31(61,62)34(67,68)37(73,74)40(79,80)43(85,86)46(91,92)93)16-13-19-1-7-22(8-2-19)100(23-9-3-20(4-10-23)14-17-26(51,52)29(57,58)32(63,64)35(69,70)38(75,76)41(81,82)44(87,88)47(94,95)96)24-11-5-21(6-12-24)15-18-27(53,54)30(59,60)33(65,66)36(71,72)39(77,78)42(83,84)45(89,90)48(97,98)99;;;/h2*1-12H,13-18H2;2*1H;/q;;;;+2/p-2

InChI key

KONKDVXTNQEYIF-UHFFFAOYSA-L

Related Categories

General description

contains up to 20% Tri(4-(1H,1H,2H,2H-perfluorodecyl)phenyl)phosphine oxide

Application

Catalyst for Stille and Suzuki couplings in Fluorous Biphase Systems (FBS)

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Perfluoro-tagged Pd complexes as catalysts for Stille couplings in a fluorous biphasic system, palladium-catalyzed Suzuki couplings.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1

target_organs

Liver

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

新产品

This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

T. Osswald et al.
Tetrahedron Letters, 42, 2965-2965 (2001)
S. Schneider et al.
Helvetica Chimica Acta, 84, 735-735 (2001)
Repetitive Application of Perfluoro-Tagged Pd Complexes for Stille Couplings in a Fluorous Biphasic System This work was supported by Fluka (Buchs) and Byk Gulden Pharmaceuticals (Konstanz). S.S. thanks Fluka for financial support. We would also thank Priv.-Doz. Dr. C. Rücker for help in the preparation of the manuscript.
Schneider et al.
Angewandte Chemie (International ed. in English), 39(22), 4142-4145 (2000-11-28)

Global Trade Item Number

SKUGTIN
95447-500MG-F04061832020570
95447-100MG-F04061832020563

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service