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Merck
CN

95447

双[三(4-(1H,1H,2H,2H-全氟癸基)苯基)膦]二氯化钯(II)

technical, ≥80% (AAS)

别名:

双[三(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟癸基)苯基)膦]二氯化钯(II)

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关于此项目

经验公式（希尔记法）:
C96H48Cl2F102P2Pd
化学文摘社编号:
326475-46-1
分子量:
3378.52
NACRES:
NA.21
PubChem Substance ID:
329770462
UNSPSC Code:
12161600
MDL number:
MFCD03453279

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InChI

1S/2C48H24F51P.2ClH.Pd/c2*49-25(50,28(55,56)31(61,62)34(67,68)37(73,74)40(79,80)43(85,86)46(91,92)93)16-13-19-1-7-22(8-2-19)100(23-9-3-20(4-10-23)14-17-26(51,52)29(57,58)32(63,64)35(69,70)38(75,76)41(81,82)44(87,88)47(94,95)96)24-11-5-21(6-12-24)15-18-27(53,54)30(59,60)33(65,66)36(71,72)39(77,78)42(83,84)45(89,90)48(97,98)99;;;/h2*1-12H,13-18H2;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc1ccc(cc1)P(c2ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc2)c3ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc3.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc4ccc(cc4)P(c5ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc5)c6ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc6

InChI key

KONKDVXTNQEYIF-UHFFFAOYSA-L

grade

technical

assay

≥80% (AAS)

form

powder

reaction suitability

reagent type: catalyst
core: palladium

mp

175-180 °C

Quality Level

100

相关类别

General description

最多包含·20% 三(4-(1H,1H,2H,2H-全氟癸基)苯基)膦氧化物

Application

氟两相体系 (FBS) 中的 Stille 和 Suzuki 偶联反应的催化剂

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

全氟标记 Pd 络合物，作为氟两相体系中 Stille 偶联反应、钯催化 Suzuki 偶联反应的催化剂。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1

target_organs

Liver

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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T. Osswald et al.
Tetrahedron Letters, 42, 2965-2965 (2001)
Repetitive Application of Perfluoro-Tagged Pd Complexes for Stille Couplings in a Fluorous Biphasic System This work was supported by Fluka (Buchs) and Byk Gulden Pharmaceuticals (Konstanz). S.S. thanks Fluka for financial support. We would also thank Priv.-Doz. Dr. C. Rücker for help in the preparation of the manuscript.
Schneider et al.
Angewandte Chemie (International ed. in English), 39(22), 4142-4145 (2000-11-28)
S. Schneider et al.
Helvetica Chimica Acta, 84, 735-735 (2001)

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