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Merck
CN

CN205869

Palladium(II) acetate

98%, reagent grade, powder

Synonym(s):

Palladium (II) acetate

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About This Item

Linear Formula:
Pd(OCOCH3)2
Molecular Weight:
224.51
MDL number:
MFCD00012453
NACRES:
NA.22
PubChem Substance ID:
24874166
UNSPSC Code:
12161600

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InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

SMILES string

CC(O[Pd]OC(C)=O)=O

grade

reagent grade

assay

98%

form

powder

reaction suitability

reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium
reaction type: Heck Reaction, reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling, reagent type: catalyst
core: palladium
reaction type: Negishi Coupling, reagent type: catalyst
core: palladium
reaction type: Sonogashira Coupling, reagent type: catalyst
core: palladium
reaction type: Stille Coupling, reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

Quality Level

200

General description

[Pd(OAc)2]3 is a palladium coordination complex and a heterogenous metal catalyst that is widely used in organic synthesis such as transmetalation, insertion, oxidative addition, direct homocoupling of aryl halides, Buchwald-Hartwig reaction of C-N bond formation, reduction of alkynes, and reductive elimination reactions. It is also employed as a starting material for the synthesis of other Pd(II) compounds as well as for the preparation of active palladium catalysts for Suzuki-Miyaura cross-coupling and C-H functionalization reactions.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions [Pd(OAc)2]3 can be used as a: Catalyst for the regioselective anti-hydrochlorination of the terminal and internal alkynes. Precursor to prepare a heterogeneous palladium complex catalyst for the Heck-Coupling reaction and Sonogashira cross-coupling reaction.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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