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About This Item
Empirical Formula (Hill Notation):
C6H10Cl2Pd2
CAS Number:
Molecular Weight:
365.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
Beilstein/REAXYS Number:
4124623
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
SMILES string
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI key
TWKVUTXHANJYGH-UHFFFAOYSA-L
reaction suitability
reagent type: catalyst
core: palladium
reaction type: C-H Activation, reagent type: catalyst
core: palladium
reaction type: Cross Couplings
Quality Level
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General description
Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.[] We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Features and Benefits
Application Guide for Palladium Catalyzed Cross-Coupling Reactions Allylpalladium(II) chloride dimer has been employed for the following studies: Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.[] Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.[] Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.[] As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
Storage Class
11 - Combustible Solids
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