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Merck
CN

D134651

Dimethoxymethane

ReagentPlus®, 99%

Synonym(s):

Formaldehyde dimethyl acetal, Methylal

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About This Item

Linear Formula:
CH2(OCH3)2
CAS Number:
Molecular Weight:
76.09
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-714-2
Beilstein/REAXYS Number:
1697025
MDL number:
Assay:
99%
Bp:
41-42 °C (lit.)
Vapor pressure:
6.38 psi ( 20 °C)
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vapor density

2.6 (vs air)

Quality Segment

vapor pressure

6.38 psi ( 20 °C)

product line

ReagentPlus®

assay

99%

form

liquid

autoignition temp.

459 °F

expl. lim.

17.6 %

dilution

(for general lab use)

refractive index

n20/D 1.354 (lit.)

bp

41-42 °C (lit.)

mp

−105 °C (lit.)

density

0.86 g/mL at 25 °C (lit.)

SMILES string

COCOC

InChI

1S/C3H8O2/c1-4-3-5-2/h3H2,1-2H3

InChI key

NKDDWNXOKDWJAK-UHFFFAOYSA-N

General description

Dimethoxymethane (DMM, methylal) is a biodegradable dimethyl acetal. It can be synthesized by acid catalyzed condensation of formaldehyde with methanol. It is amphiphilic in nature with low viscosity, surface tension and boiling point. It is a flammable, highly volatile solvent with good dissolving power. DMM is considered as a potential alternative fuel and fuel additive due to its high oxygen content and its ability to enhance the combustion characteristics of diesel and petrol. Its thermal diffusivity has been determined by photoacoustic method. Analysis of the molecular structure of DMM by electron diffraction technique shows that it has C2 symmetry with a gauche-gauche conformation.

Application

Dimethoxymethane (Formaldehyde dimethyl acetal) may be used in the synthesis of methoxymethyl (MOM) ethers. It may also be used as an external cross-linker to form microporous polymers.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-0.4 °F - closed cup

flash_point_c

-18 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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