207896
Copper(II) carbonate basic
reagent grade
Synonym(s):
Cupric carbonate basic
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About This Item
Linear Formula:
CuCO3 · Cu(OH)2
CAS Number:
Molecular Weight:
221.12
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
235-113-6
MDL number:
Grade:
reagent grade
Form:
powder
InChI key
ZMMDPCMYTCRWFF-UHFFFAOYSA-J
InChI
1S/CH2O3.2Cu.2H2O/c2-1(3)4;;;;/h(H2,2,3,4);;;2*1H2/q;2*+2;;/p-4
SMILES string
[Cu++].O[Cu]O.[O-]C([O-])=O
grade
reagent grade
form
powder
concentration
50.0-57.0% Cu (EDTA titration)
Quality Level
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Application
Copper(II) carbonate basic (Cupric carbonate basic, Copper(II) basic carbonate) may be used in the preparation of colloidal copper.
Copper(II) carbonate basic along with different ligands form an efficient catalytic system for ′on water′ β-borylation of Michael acceptors, alkenes and alkynes.
General description
Copper(II) carbonate basic is naturally found in azurite and malachite. On heating, it undergoes decomposition to form copper(II) oxide, carbon dioxide and water. Due to its high initial discharge capacity, copper(II) carbonate (basic) is being considered as a promising candidate as anode materials for lithium-ion batteries.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
does not flash
flash_point_c
does not flash
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Preparation and characterization of basic carbonates as novel anode materials for lithium-ion batteries.
Shao L, et al.
Ceramics International, 40(2), 3105-3116 (2014)
Gerrans GC, et al.
Sasol Encyclopaedia of Science and Technology (2004)
Basic CuCO3/ligand as a new catalyst for'on water'borylation of Michael acceptors, alkenes and alkynes: application to the efficient asymmetric synthesis of ?-alcohol type sitagliptin side chain.
Stavber G and Casar Z.
Applied Organometallic Chemistry, 27(3), 159-165 (2013)
Preparation and characterization of uniform particles of pure and coated metallic copper.
Hsu WP, et al.
Powder Technology, 63(3), 265-275 (1990)
Daintith J
The facts on file dictionary of chemistry, 60-60 (2014)
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