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210250

Hydroxylamine sulfate

99%

Synonym(s):

Hydroxylammonium sulfate

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About This Item

Linear Formula:
(NH2OH)2 · H2SO4
CAS Number:
10039-54-0
Molecular Weight:
164.14
NACRES:
NA.21
PubChem Substance ID:
329751902
UNSPSC Code:
12352100
EC Number:
233-118-8
MDL number:
MFCD00044869
Assay:
99%
Form:
crystals
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Quality Level

200

assay

99%

form

crystals

mp

170 °C (dec.) (lit.)

SMILES string

NO.NO.OS(O)(=O)=O

InChI

1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)

InChI key

VRXOQUOGDYKXFA-UHFFFAOYSA-N

General description

Cyclohexanone oxime undergoes hydrolytic reaction with sulfuric acid to yield hydroxylamine sulfate. It reacts with sulfur dioxide to afford sulfamic acid.

Application

Hydroxylamine sulfate may be used in the following:
  • Along with NaCl for reduction during the atomic absorption spectrophotometric quantification of mercury at ppb (parts-per-billion) levels in solution.
  • As one of the constituents during the preparation of a coloring solution, impregnated in a cellulose based monitoring tape for the sensitive detection of formaldehyde gas.
  • Simultaneous estimation of hydrarine and hydroxylamine in mixtures by titration with alkaline ferricyanide in presence of zinc sulfate.
Powerful reducing agent. Converts aldehydes and ketones to oximes, and acid chlorides to hydroxamic acids. Used as catalyst, swelling agent, and copolymerization inhibitor in polymerization processes.

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Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral

target_organs

Blood

Storage Class

4.1A - Other explosive hazardous materials

wgk

WGK 3

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB2961
MKCZ8561
MKCZ4961
MKCZ2322
MKCX6547

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A simple and efficient approach for preparation of hydroxylamine sulfate from the acid-catalyzed hydrolysis reaction of cyclohexanone oxime.
Zhao, Fangfang, et al.
Chemical Engineering Journal, 272, 102-107 (2015)
The Preparation of Sulfamic Acid by the Hydroxylamine--Sulfur Dioxide Reaction.
Sisler HH and Audrieth LF.
Journal of the American Chemical Society, 61(12), 3389-3391 (1939)
Development of a monitoring tape for formaldehyde using hydroxylamine sulfate and methyl yellow.
NAKANO N, et al.
Analytical Sciences, 10(4), 641-645 (1994)
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Global Trade Item Number

SKUGTIN
210250-1KG04061838771209
210250-100G04061838771193