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Merck
CN

221163

Silver(I) oxide

ReagentPlus®, 99%

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About This Item

Empirical Formula (Hill Notation):
Ag2O
CAS Number:
Molecular Weight:
231.74
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
243-957-1
MDL number:
Assay:
99%
Form:
powder or chunks
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Quality Level

product line

ReagentPlus®

assay

99%

form

powder or chunks

reaction suitability

reagent type: catalyst
core: silver

SMILES string

[Ag]O[Ag]

InChI

1S/2Ag.O

InChI key

KHJDQHIZCZTCAE-UHFFFAOYSA-N

Application

Mediates monoprotection of symmetrical diols with alkyl halides in good to excellent yield.
Silver(I) oxide may be used to mediate the following processes:
  • Selective monoalkylation of symmetric diols in the presence of alkyl halide.
  • Palladium catalyzed cross-coupling of aryl- and alkenylsilanols with organic halides.
  • Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alkynes to form arylated or alkenylated alkynes, respectively.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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Highly selective silver (I) oxide mediated monoprotection of symmetrical diols
Bouzide A and Sauve G.
Tetrahedron Letters, 38(34), 5945-5948 (1997)
A New Transformation of Silanols. Palladium-Catalyzed Cross-Coupling with Organic Halides in the Presence of Silver (I) Oxide
Hirabayashi K, et al.
Organic Letters, 1(2), 299-302 (1999)
Eagleson M.
Concise Encyclopedia Chemistry, 90-90 (1994)



Global Trade Item Number

SKUGTIN
221163-1KG04061838776976
221163-10G04061838776969
221163-50G04061838776990
221163-250G04061838776983