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Sigma-Aldrich

Calcium carbonate

ACS reagent, ≥99.0%, powder

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Linear Formula:
CaCO3
CAS Number:
471-34-1
Molecular Weight:
100.09
Beilstein:
8008338
EC Number:
207-439-9
MDL number:
MFCD00010906
PubChem Substance ID:
329752519
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

Assay

≥99.0%

form

powder

impurities

≤0.002 meq/g water-soluble titr. base
≤0.005% oxidizers
≤0.01% NH4OH pptd.
≤0.01% insol. dil. HCl

pH

8

density

2.93 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
fluoride (F-): ≤0.0015%
sulfate (SO42-): ≤0.01%

cation traces

Ba: ≤0.005%
Fe: ≤0.003%
K: ≤0.01%
Mg: ≤0.02%
NH4+: ≤0.003%
Na: ≤0.1%
Sr: ≤0.1%
heavy metals: ≤0.001% (by ICP-OES)

SMILES string

[Ca++].[O-]C([O-])=O

InChI

1S/CH2O3.Ca/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2

InChI key

VTYYLEPIZMXCLO-UHFFFAOYSA-L

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General description

CaCO3 occurs naturally as the principal constituent of limestone, marble, and chalk, which can be prepared by the precipitation from dissolved calcium hydroxide and carbon dioxide.

Application

Calcium carbonate can be used as a precursor to prepare Pd/CaCO3, which can be used as a catalyst:
  • In Miyaura-Suzuki cross-coupling reactions.
  • In the ligand-free Stille cross-coupling reaction between aryl halides and tributylphenyltin to synthesize biphenyls.
It can also be used as a base in the Pd-catalyzed regioselective Heck reaction of fluorinated haloaryls with olefins to synthesize substituted olefins.

Other Notes

Go to Redi-Dri™ Product Listing 795445

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Michał M Kłosowski et al.
Acta biomaterialia, 20, 129-139 (2015-04-08)
To devise new strategies to treat bone disease in an ageing society, a more detailed characterisation of the process by which bone mineralises is needed. In vitro studies have suggested that carbonated mineral might be a precursor for deposition of
Robert J Friederichs et al.
Journal of the Royal Society, Interface, 12(108), 20150190-20150190 (2015-06-05)
Experimental chemistry and atomic modelling studies were performed here to investigate a novel ionic co-substitution in hydroxyapatite (HA). Zinc, silicate co-substituted HA (ZnSiHA) remained phase pure after heating to 1100 °C with Zn and Si amounts of 0.6 wt% and
Denis Gebauer et al.
Nanoscale, 3(9), 3563-3566 (2011-08-19)
Nanocellulose hybrids are promising candidates for biodegradable multifunctional materials. Hybrids of nanocrystalline cellulose (NCC) and amorphous calcium carbonate (ACC) nanoparticles were obtained through a facile chemical approach over a wide range of compositions. Controlling the interactions between NCC and ACC
Eagleson M.
Concise Encyclopedia Chemistry, 162-162 (1994)
M Azizur Rahman et al.
PloS one, 8(3), e58781-e58781 (2013-03-26)
An organic matrix consisting of a protein-polysaccharide complex is generally accepted as an important medium for the calcification process. While the role this "calcified organic matrix" plays in the calcification process has long been appreciated, the complex mixture of proteins
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