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Merck
CN

239216

Calcium carbonate

ACS reagent, ≥99.0%, powder

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About This Item

Linear Formula:
CaCO3
CAS Number:
471-34-1
Molecular Weight:
100.09
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
329752519
EC Number:
207-439-9
Beilstein/REAXYS Number:
8008338
MDL number:
MFCD00010906
Assay:
≥99.0%
Grade:
ACS reagent
Form:
powder

Key Documents

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Product Name

Calcium carbonate, ACS reagent, ≥99.0%, powder

InChI key

VTYYLEPIZMXCLO-UHFFFAOYSA-L

InChI

1S/CH2O3.Ca/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2

SMILES string

[Ca++].[O-]C([O-])=O

grade

ACS reagent

assay

≥99.0%

form

powder

impurities

≤0.002 meq/g water-soluble titr. base
≤0.005% oxidizers
≤0.01% NH4OH pptd.
≤0.01% insol. dil. HCl

pH

8

density

2.93 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
fluoride (F-): ≤0.0015%
sulfate (SO42-): ≤0.01%

cation traces

Ba: ≤0.005%
Fe: ≤0.003%
K: ≤0.01%
Mg: ≤0.02%
NH4+: ≤0.003%
Na: ≤0.1%
Sr: ≤0.1%
heavy metals: ≤0.001% (by ICP-OES)

Quality Level

200

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General description

CaCO3 occurs naturally as the principal constituent of limestone, marble, and chalk, which can be prepared by the precipitation from dissolved calcium hydroxide and carbon dioxide.

Other Notes

Go to Redi-Dri™ Product Listing 795445

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Application

Calcium carbonate can be used as a precursor to prepare Pd/CaCO3, which can be used as a catalyst:
  • In Miyaura-Suzuki cross-coupling reactions.
  • In the ligand-free Stille cross-coupling reaction between aryl halides and tributylphenyltin to synthesize biphenyls.
It can also be used as a base in the Pd-catalyzed regioselective Heck reaction of fluorinated haloaryls with olefins to synthesize substituted olefins.

Storage Class

11 - Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
0000517613
0000517613
MKCZ7560
0000476577
0000476577

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Michał M Kłosowski et al.
Acta biomaterialia, 20, 129-139 (2015-04-08)
To devise new strategies to treat bone disease in an ageing society, a more detailed characterisation of the process by which bone mineralises is needed. In vitro studies have suggested that carbonated mineral might be a precursor for deposition of
Robert J Friederichs et al.
Journal of the Royal Society, Interface, 12(108), 20150190-20150190 (2015-06-05)
Experimental chemistry and atomic modelling studies were performed here to investigate a novel ionic co-substitution in hydroxyapatite (HA). Zinc, silicate co-substituted HA (ZnSiHA) remained phase pure after heating to 1100 °C with Zn and Si amounts of 0.6 wt% and
Denis Gebauer et al.
Nanoscale, 3(9), 3563-3566 (2011-08-19)
Nanocellulose hybrids are promising candidates for biodegradable multifunctional materials. Hybrids of nanocrystalline cellulose (NCC) and amorphous calcium carbonate (ACC) nanoparticles were obtained through a facile chemical approach over a wide range of compositions. Controlling the interactions between NCC and ACC
Eagleson M.
Concise Encyclopedia Chemistry, 162-162 (1994)
M Azizur Rahman et al.
PloS one, 8(3), e58781-e58781 (2013-03-26)
An organic matrix consisting of a protein-polysaccharide complex is generally accepted as an important medium for the calcification process. While the role this "calcified organic matrix" plays in the calcification process has long been appreciated, the complex mixture of proteins
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