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Sigma-Aldrich

Sodium bromide

ACS reagent, ≥99.0%

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Linear Formula:
NaBr
CAS Number:
7647-15-6
Molecular Weight:
102.89
EC Number:
231-599-9
MDL number:
MFCD00003475
eCl@ss:
38050404
PubChem Substance ID:
329753628
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

Agency

suitable for EPA 300

vapor pressure

1 mmHg ( 806 °C)

Assay

≥99.0%

form

powder, crystals or granules

impurities

≤0.005% insolubles

pH

5.0-8.8 (25 °C, 5%)

mp

755 °C (lit.)

solubility

ethanol: soluble(lit.)
water: soluble(lit.)

anion traces

bromate (BrO3-): ≤0.001%
chloride (Cl-): ≤0.2%
sulfate (SO42-): ≤0.002%

cation traces

Ba: ≤0.002%
Ca: ≤0.002%
Fe: ≤5 ppm
K: ≤0.1%
Mg: ≤0.001%
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

[Na+].[Br-]

InChI

1S/BrH.Na/h1H;/q;+1/p-1

InChI key

JHJLBTNAGRQEKS-UHFFFAOYSA-M

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General description

Sodium Bromide is an inorganic compound that is commonly used as a source of bromide ions as a nucleophile or nucleophilic catalyst. It is also used as a precursor to reactive electrophilic bromine species, which are useful for a variety of organic transformations.

Application

Sodium Bromide can be used as a catalyst in TEMPO-mediated oxidation reactions. It is also used to grow the single crystal of γ-glycine by the slow cooling method.

Other Notes

Go to Redi-Dri™ Product Listing 793574

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictograms

Exclamation markHealth hazard
GHS07,GHS08

Signal Word

Warning

Hazard Statements

H336 - H361fd - H373

Hazard Classifications

Repr. 2 - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Eagleson M.
Concise Encyclopedia Chemistry, 996-996 (1994)
Ling Yue et al.
Applied biochemistry and biotechnology, 175(7), 3557-3570 (2015-02-05)
A novel aqueous two-phase system (ATPS) only containing Gemini surfactant ethanediyl-1,2-bis(dodecyldimethylammonium bromide) and an inorganic salt sodium bromide was designed, and the physicochemical properties of the ATPS were investigated systematically. The results have shown that the coexisting two phases, one
Sergiu Coseri et al.
Carbohydrate polymers, 116, 9-17 (2014-12-03)
Unoxidized and carboxylated pullulan (obtained by pullulan oxidation using TEMPO-sodium hypochlorite-sodium bromide system) have been used as mediators for the silver nanoparticles formation (AgNPs), under environment-friendly conditions: using aqueous solutions, room temperature and notably, by using both mediators as reducing
Sodium bromide catalysed one-pot synthesis of tetrahydrobenzo [b] pyrans via a three-component cyclocondensation under microwave irradiation and solvent free conditions.
Devi I and Bhuyan PJ.
Tetrahedron Letters, 45(47), 8625-8627 (2004)
Julian Holley et al.
Physical review. E, Statistical, nonlinear, and soft matter physics, 84(5 Pt 2), 056110-056110 (2011-12-21)
Excitation waves on a subexcitable Belousov-Zhabotinsky (BZ) substrate can be manipulated by chemical variations in the substrate and by interactions with other waves. Symbolic assignment and interpretation of wave dynamics can be used to perform logical and arithmetic computations. We
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