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Merck
CN

31494

Silver sulfate

puriss. p.a., ACS reagent, ≥99.5%

Synonym(s):

Sulfuric acid disilver(I) salt

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About This Item

Linear Formula:
Ag2SO4
CAS Number:
Molecular Weight:
311.80
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-653-7
MDL number:
Assay:
≥99.5%
Form:
crystalline
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Quality Segment

grade

ACS reagent, puriss. p.a.

assay

≥99.5%

form

crystalline

impurities

≤0.02% Insoluble matter and silver chloride, ≤0.03% substances not precipitated by HCl

mp

652 °C (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg, nitrate (NO3-): ≤10 mg/kg

cation traces

Ca: ≤50 ppm, Cd: ≤50 ppm, Co: ≤50 ppm, Cu: ≤5 ppm, Fe: ≤10 ppm, K: ≤100 ppm, Na: ≤200 ppm, Ni: ≤10 ppm, Pb: ≤10 ppm, Zn: ≤5 ppm

SMILES string

[Ag+].[Ag+].[O-]S([O-])(=O)=O

InChI

1S/2Ag.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2

InChI key

YPNVIBVEFVRZPJ-UHFFFAOYSA-L

General description

Silver sulfate (Ag2SO4) is a disilver(I) salt of sulfuric acid. It participates in the TiO2-assisted photooxidation of substituted benzyltrimethylsilanes in acetonitrile. Diarylethanes were obtained in 50-74% yields.

Application

Silver sulfate may be employed in the preparation of the following:
  • Iodination reagent in combination with iodine for the synthesis of iododerivatives.
  • Silver sulfate reagent, which is required for the determination of Chemical Oxygen Demand (COD).


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Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Codes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

Storage Class

11 - Combustible Solids



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