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Merck
CN

383090

Ammonium cerium(IV) sulfate dihydrate

ACS reagent, ≥94%

Synonym(s):

Ceric ammonium sulfate, Cerium(IV) ammonium sulfate

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About This Item

Linear Formula:
Ce(NH4)4(SO4)4 · 2H2O
CAS Number:
10378-47-9
Molecular Weight:
632.55
MDL number:
MFCD00149417
UNSPSC Code:
12352302
PubChem Substance ID:
329755666
NACRES:
NB.24
Assay:
≥94%
Grade:
ACS reagent
Form:
powder or crystals

Key Documents

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grade

ACS reagent

Assay

≥94%

form

powder or crystals

reaction suitability

reagent type: catalyst
core: cerium

impurities

≤0.05% insol. dil. H2SO4

mp

130 °C (lit.)

anion traces

phosphate (PO43-): ≤0.03%

cation traces

Fe: ≤0.01%

SMILES string

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

InChI key

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

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General description

Ammonium cerium(IV) sulfate dehydrate is a cerium salt widely used in the volumetric analysis.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
0000470745
0000470745
MKCX7222
MKCX8061
MKCX6390

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Cerium-initiated grafting of acrylonitrile onto cellulosic materials.
Hebeish A and Mehta PC.
Journal of Applied Polymer Science, 12(7), 1625-1647 (1968)
Analysis of phenolic compounds in health care products by low-pressure liquid-chromatography with monolithic column and chemiluminescent detection.
Ballesta-Claver J, et al.
Luminescence, 26(1), 44-53 (2011)
Self-Poled Transparent and Flexible UV Light-Emitting Cerium Complex-PVDF Composite: A High-Performance Nanogenerator.
Garain S, et al.
ACS Applied Materials & Interfaces, 7(2), 1298-1307 (2015)
David CA and Hellier DG
Dictionary of Environmentally Important Chemicals, 92-92 (1997)
Kanakapura Basavaiah et al.
Acta pharmaceutica (Zagreb, Croatia), 57(2), 211-220 (2007-05-18)
Two spectrophotometric methods are proposed for the assay of lansoprazole (LPZ) in bulk drug and in dosage forms using ceric ammonium sulphate (CAS) and two dyes, methyl orange and indigo carmine, as reagents. The methods involve addition of a known
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