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Merck
CN

404985

Titanium(IV) chloride solution

0.09 M in 20% HCl

Synonym(s):

Titanium tetrachloride

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About This Item

Linear Formula:
TiCl4
CAS Number:
7550-45-0
Molecular Weight:
189.68
NACRES:
NA.21
PubChem Substance ID:
329755994
UNSPSC Code:
12352300
MDL number:
MFCD00011267
Form:
liquid

Key Documents

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Product Name

Titanium(IV) chloride solution, 0.09 M in 20% HCl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.09 M in 20% HCl

density

1.099 g/mL at 25 °C

Quality Level

100

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Application

Reagent for the detection of peroxides in ethyl ether. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Titanium(IV) chloride (TiCl4) solution may be used to synthesize nanosized titanium dioxide and nano/micro-sized titania powders.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

易制毒化学品（3类）
危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ5313
MKCW9994
MKCT6920
MKCR7314
MKCQ1246

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Titanium tetrachloride promoted hydrolysis of cephalosporin tert-butyl esters.
Valencic M, et al.
Tetrahedron Letters, 39(12), 1625-1628 (1998)
Influence of solution concentration on the hydrothermal preparation of titania crystallites.
Yanqing Z, et al.
Journal of Materials Chemistry, 11(5), 1547-1551 (2001)
Reagent Chemicals (1992)
Mechanism of enhanced performance of dye-sensitized solar cell based TiO2 films treated by titanium tetrachloride.
Long-Yue Z, et al.
Chinese Physics Letters, 21(9), 1835-1835 (2004)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
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