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Merck
CN

404985

Titanium(IV) chloride solution

0.09 M in 20% HCl

Synonym(s):

Titanium tetrachloride

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About This Item

Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Form:
liquid
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form

liquid

Quality Level

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.09 M in 20% HCl

density

1.099 g/mL at 25 °C

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

Application

Reagent for the detection of peroxides in ethyl ether. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Titanium(IV) chloride (TiCl4) solution may be used to synthesize nanosized titanium dioxide and nano/micro-sized titania powders.


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

易制毒化学品(3类)
危险化学品

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Titanium tetrachloride promoted hydrolysis of cephalosporin tert-butyl esters.
Valencic M, et al.
Tetrahedron Letters, 39(12), 1625-1628 (1998)
Reagent Chemicals (1992)
Influence of solution concentration on the hydrothermal preparation of titania crystallites.
Yanqing Z, et al.
Journal of Materials Chemistry, 11(5), 1547-1551 (2001)



Global Trade Item Number

SKUGTIN
404985-100ML04061831987089
404985-4X100ML04061837633836