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Merck
CN

A0627

Sigma-Aldrich

Adenosine-5′-diphosphoglucose disodium salt

≥93%, from yeast, powder

Synonym(s):

ADP, ADP-Glucose, ADP-glc, ADPG

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About This Item

Empirical Formula (Hill Notation):
C16H23N5Na2O15P2
CAS Number:
102129-65-7
Molecular Weight:
633.31
MDL number:
MFCD00056005
UNSPSC Code:
41106305
PubChem Substance ID:
24890440
NACRES:
NA.51

Key Documents

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Product Name

Adenosine-5′-diphosphoglucose disodium salt, ≥93%

biological source

yeast

Quality Level

200

Assay

≥93%

form

powder

solubility

water: 50 mg/mL, clear, colorless to very faintly yellow

storage temp.

−20°C

SMILES string

[Na+].[Na+].Nc1ncnc2n(cnc12)[C@@H]3O[C@H](COP([O-])(=O)OP([O-])(=O)OC4O[C@H](CO)[C@@H](O)[C@H](O)[C@H]4O)[C@@H](O)[C@H]3O

InChI

1S/C16H25N5O15P2.2Na/c17-13-7-14(19-3-18-13)21(4-20-7)15-11(26)9(24)6(33-15)2-32-37(28,29)36-38(30,31)35-16-12(27)10(25)8(23)5(1-22)34-16;;/h3-6,8-12,15-16,22-27H,1-2H2,(H,28,29)(H,30,31)(H2,17,18,19);;/q;2*+1/p-2/t5-,6-,8-,9-,10+,11-,12-,15-,16?;;/m1../s1

InChI key

GZBIVALVIPYODS-UQGWVDHFSA-L

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Application

Adenosine-5′-diphosphoglucose (ADP-Glucose) is a substrate widely used as a glucose donor. It is a substrate in starch synthesis by starch synthase (EC 2.4.1.21). ADP-Glucose is a substrate for alpha-1,4-glucan-protein synthase (ADP-forming) (EC 2.4.1.113), ADP-glucose pyrophosphorylases and many glucosyltransferases.
Adenosine-5′-diphosphoglucose disodium salt has been used as a component of the reaction mixture to measure the enzymatic activity of adenosine-5′-diphosphate (ADP)-glucose pyrophosphorylase (AGPase) and for the synthesis of starch.

Biochem/physiol Actions

Adenosine-5′-diphosphoglucose (ADP-Glucose) is a substrate widely used as a glucose donor. It is a substrate starch synthase (EC 2.4.1.21) in starch synthesis. ADP-glucose is a substrate for α-1,4-glucan-protein synthase (ADP-forming) (EC 2.4.1.113), ADP-glucose pyrophosphorylases and many glucosyltransferases.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

涉药品监管产品
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Certificates of Analysis (COA)

Lot/Batch Number
0000461445
0000461445
0000427858
0000427858
0000393637

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Carlos M Figueroa et al.
Frontiers in plant science, 9, 1564-1564 (2018-11-15)
ADP-glucose pyrophosphorylase (ADP-Glc PPase) catalyzes the first committed step for the synthesis of glycogen in cyanobacteria and starch in green algae and plants. The enzyme from cyanobacteria is homotetrameric (α4), while that from green algae and plants is heterotetrameric (α2β2).
Guohui Li et al.
Frontiers in plant science, 9, 1128-1128 (2018-08-16)
More than 4 billion inhabitants in Asia depend on rice for 35-60% of the calories consumed in their diets, but new rice cultivars frequently do not reach expected yields because of poor rice grain filling. Here, we quantified the activities
ADP-glucose pyrophosphorylase, a regulatory enzyme for bacterial glycogen synthesis
Ballicora MA, et al.
Microbiology and Molecular Biology Reviews, 67(2), 213-225 (2003)
Analysis of Starch Synthase Activities in Wheat Grains using Native-PAGE
Li Z
Bio-protocol (2016)
Steven Ball et al.
Journal of experimental botany, 62(6), 1775-1801 (2011-01-12)
Solid semi-crystalline starch and hydrosoluble glycogen define two distinct physical states of the same type of storage polysaccharide. Appearance of semi-crystalline storage polysaccharides appears linked to the requirement of unicellular diazotrophic cyanobacteria to fuel nitrogenase and protect it from oxygen
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