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Merck
CN

S5505

Silica, fumed

powder, 0.2-0.3 μm avg. part. size (aggregate)

Synonym(s):

Silica, Silicic anhydride, Silicon dioxide, Silicon dioxide amorphous

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About This Item

Linear Formula:
SiO2
CAS Number:
Molecular Weight:
60.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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form

powder

Quality Segment

surface area

200 m2/g (±25 m2/g)

refractive index

n20/D 1.46 (lit.)

avg. part. size

0.2-0.3 μm (aggregate)

density

2.3 lb/cu.ft at 25 °C (bulk density)(lit.)

SMILES string

O=[Si]=O

InChI

1S/O2Si/c1-3-2

InChI key

VYPSYNLAJGMNEJ-UHFFFAOYSA-N

Application

Fumed Silica (SiO2) has been used as a precursor to synthesize:
  • Chlorosilanes via silanization, which are used to prepare silica/polydimethylsiloxane membranes to study permeation performance.
  • Silicon carbide (SiC) nanoparticles by sol-gel method.
  • Calcium silicate hydrate (C-S-H) by treating with CaO and water via hydrothermal reaction.
  • Si/PtO2 catalyst for the selective conversion of cinnamaldehyde to cinnamic acid by aerobic oxidation.


It can be also used in the preparation of:
  • Silica sulfuric acid catalyst used in the synthesis of 3,4-dihydropyrimidin-2(1H)-ones via one-pot three-component Biginelli reaction.
  • HClO4-SiO2 heterogeneous catalyst used in the synthesis of tetrasubstituted imidazoles.

Features and Benefits

Has interesting thickening and thixotropic properties, and an enormous external surface area.

Other Notes

Particle sizes are for primary particles, which form branched, chain-like aggregates a few tenths of a micron long.


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Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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