CRM67566
Metalaxyl-M
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(s):
N-(2,6-Dimethylphenyl)-N-(methoxyacetyl)-D-alanine methyl ester, Mefenoxam
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About This Item
Empirical Formula (Hill Notation):
C15H21NO4
CAS Number:
Molecular Weight:
279.33
UNSPSC Code:
41116107
NACRES:
NA.24
MDL number:
Quality Level
product line
TraceCERT®
grade
certified reference material, TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
SMILES string
COCC(=O)N([C@H](C)C(=O)OC)c1c(C)cccc1C
InChI
1S/C15H21NO4/c1-10-7-6-8-11(2)14(10)16(13(17)9-19-4)12(3)15(18)20-5/h6-8,12H,9H2,1-5H3/t12-/m1/s1
InChI key
ZQEIXNIJLIKNTD-GFCCVEGCSA-N
General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Metalaxyl-M is the R-enantiomer of the systemic fungicide metalaxyl. It is a widely used acetylalanine fungicide.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, metalaxyl-M is approved for use as a plant protection agent in the European Union. The Commission Regulation (EU) 2020/617 of 5th May 2020 renewed the approval of use for metalaxyl-M in products of plant origin until 31st May 2035. The Reg. (EU) 2017/1164 sets a maximum residue limit (MRL) of 0.7 mg/kg and 0.01 mg/kg in fresh/frozen fruits and tree nuts respectively for metalaxyl including other mixtures of constituent isomers including metalaxyl-M (sum of isomers).
Metalaxyl-M has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Metalaxyl-M is the R-enantiomer of the systemic fungicide metalaxyl. It is a widely used acetylalanine fungicide.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, metalaxyl-M is approved for use as a plant protection agent in the European Union. The Commission Regulation (EU) 2020/617 of 5th May 2020 renewed the approval of use for metalaxyl-M in products of plant origin until 31st May 2035. The Reg. (EU) 2017/1164 sets a maximum residue limit (MRL) of 0.7 mg/kg and 0.01 mg/kg in fresh/frozen fruits and tree nuts respectively for metalaxyl including other mixtures of constituent isomers including metalaxyl-M (sum of isomers).
Metalaxyl-M has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The metalaxyl-M CRM may also find following uses:
The metalaxyl-M CRM may also find following uses:
- Mixed-mode solid phase extraction (SPE) and liquid chromatographic-mass spectrometric (LC-MS) determination of 9 fungicides in red and white wine samples
- Analyze the uptake and distribution of two fungicides and two insecticides in greenhouse grown chrysanthemum by QuEChERS-based extraction from the root, stem, leaf, flower, and soil samples, followed by an UPLC-MS/MS determination
- Simultaneous determination of six fungicides residues in grape, wine, and raisin samples by HPLC-MS/MS
- Separation of 21 chiral pesticides by supercritical fluid chromatography-mass spectrometry (SFC-ESIMS/MS) from tomato, orange, leek, and cayenne samples
- Investigation of 109 pesticide residues in gherkin samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-tandem mass spectrometry (GC-MS/MS)
- Multi-residue analysis of 58 pesticide residues in water samples by extraction using solvent-based de-emulsification dispersive liquid-liquid microextraction (SD-DLLME) and determination by liquid chromatography-tandem mass spectrometry (LC-MS/MS)
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1
Storage Class
10 - Combustible liquids
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
农药列管产品
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Certificates of Analysis (COA)
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Quantification of pesticide residues in gherkins by liquid and gas chromatography coupled to tandem mass spectrometry
Golge O, et al.
Journal of food composition and analysis, 96, 103755-103755 (2021)
Rapid analysis and residue evaluation of six fungicides in grape wine-making and drying
Hou X, et al.
Journal of food composition and analysis, 89, 103465-103465 (2020)
I Carpinteiro et al.
Journal of chromatography. A, 1217(48), 7484-7492 (2010-10-26)
A novel procedure for the determination of nine selected fungicides (metalaxyl-M, azoxystrobin, myclobutanil, flusilazole, penconazole, tebuconazole, propiconazole, diniconazole and difenoconazole) in wine samples is presented. Sample enrichment and purification is simultaneously performed using mixed-mode, anion exchange and reversed-phase, OASIS MAX
Global Trade Item Number
| SKU | GTIN |
|---|---|
| CRM67566-100MG | 04065265038393 |