02615
(乙氧基羰基甲基)三苯基氯化膦
technical, ≥90% (AT)
别名:
(2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride
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关于此项目
线性分子式:
CH3CH2OCOCH2P(Cl)(C6H5)3
化学文摘社编号:
分子量:
384.84
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-548-2
Beilstein/REAXYS Number:
3924139
MDL number:
产品名称
(乙氧基羰基甲基)三苯基氯化膦, technical, ≥90% (AT)
InChI key
DJGHVEPNEJKZBF-UHFFFAOYSA-M
InChI
1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
SMILES string
[Cl-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
grade
technical
assay
≥90% (AT)
reaction suitability
reaction type: C-C Bond Formation
mp
120-123 °C (dec.)
120-123 °C (lit.)
functional group
ester
phosphine
storage temp.
2-8°C
Quality Level
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Other Notes
制备 Wittig 试剂的原料
Application
Reactant for:
- Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
- Ring-opening reactions with Wittig reagents
- Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
- Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
- Preparation of phosphonium derivatives of coumarin
hcodes
signalword
Warning
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
O. Sieber et al.
Helvetica Chimica Acta, 40, 1242-1242 (1957)
H.J. Bestmann et al.
Chemische Berichte, 96, 465-465 (1963)
H. Moison et al.
Tetrahedron, 43, 537-537 (1987)
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