100331
氯甲基甲醚
technical grade
别名:
MOM chloride, 氯甲氧基甲烷, 甲基氯甲醚
等级
technical grade
质量水平
蒸汽压
3.55 psi ( 20 °C)
方案
≥92.5%
表单
liquid
折射率
n20/D 1.396 (lit.)
沸点
55-57 °C ((lit.))
55-57 °C (lit.)
密度
1.06 g/mL at 25 °C (lit.)
1.06 g/mL at 25 °C
官能团
chloro
ether
储存温度
2-8°C
SMILES字符串
COCCl
InChI
[1S/C2H5ClO/c1-4-2-3/h2H2,1H3]
1S/C2H5ClO/c1-4-2-3/h2H2,1H3
InChI key
[XJUZRXYOEPSWMB-UHFFFAOYSA-N]
XJUZRXYOEPSWMB-UHFFFAOYSA-N
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应用
Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
- For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
- To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.
- In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
60.8 °F - closed cup
闪点(°C)
16 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
监管及禁止进口产品
Synthesis and reactivity of new (methoxy) methyl complexes of manganese (I) and rhenium (I)
Hevia E, et al.
Organometallics, 25(20), 4909-4912 (2006)
Bis(chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 12, 71-73 (2011-08-19)
Martin A Berliner et al.
The Journal of organic chemistry, 70(23), 9618-9621 (2005-11-05)
[Reaction: see text]. Zinc(II) salts catalyze the reaction between acetals and acid halides to provide haloalkyl ethers in near-quantitative yield. Reactions from millimole to mole scale are typically complete in 1-4 h with 0.01 mol % catalyst. The solutions of
Bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 11, III56-III57 (2004-01-01)
Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
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