100331
氯甲基甲醚
technical grade
别名:
MOM chloride, 氯甲氧基甲烷, 甲基氯甲醚
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关于此项目
线性分子式:
ClCH2OCH3
化学文摘社编号:
分子量:
80.51
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
EC Number:
203-480-1
MDL number:
Assay:
≥92.5%
Form:
liquid
产品名称
氯甲基甲醚, technical grade
InChI
[1S/C2H5ClO/c1-4-2-3/h2H2,1H3]
1S/C2H5ClO/c1-4-2-3/h2H2,1H3
InChI key
[XJUZRXYOEPSWMB-UHFFFAOYSA-N]
XJUZRXYOEPSWMB-UHFFFAOYSA-N
SMILES string
COCCl
grade
technical grade
vapor pressure
3.55 psi ( 20 °C)
assay
≥92.5%
form
liquid
refractive index
n20/D 1.396 (lit.)
bp
55-57 °C ((lit.))
55-57 °C (lit.)
density
1.06 g/mL at 25 °C (lit.)
1.06 g/mL at 25 °C
functional group
chloro
ether
storage temp.
2-8°C
Quality Level
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Application
Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
- For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
- To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.
- In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
监管及禁止进口产品
此项目有
A Blair et al.
Cancer causes & control : CCC, 8(3), 473-490 (1997-05-01)
Epidemiologic evidence on the relation between reactive chemicals and cancer is reviewed. These highly reactive chemicals (acrylonitrile; bis[chloromethyl]ether and chloromethyl methyl ether; 1,3-butadiene, ethylene oxide; formaldehyde; mustard gas; sulfuric acid; and vinyl chloride) vary in use and exposure. All are
Organometallics, 25, 4909-4909 (2006)
A modified low-cost preparation of chloromethyl methyl ether (MOM-Cl)
Reggelin M and Doerr S
Synlett, 2004(06), 1117-1117 (2004)
Friedel-Crafts polymerization of fluorene with methylene chloride, methoxyacetyl chloride, and chloromethyl methyl ether
Nystuen NJ and Jones MB
Journal of Polymer Science, 23(5), 1433-1444 (1985)
Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
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