101834
环己烷羧酸
98%
别名:
六氢苯甲酸
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线性分子式:
C6H11CO2H
化学文摘社编号:
分子量:
128.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-711-3
Beilstein/REAXYS Number:
970529
MDL number:
Assay:
98%
Form:
solid
产品名称
环己烷羧酸, 98%
InChI key
NZNMSOFKMUBTKW-UHFFFAOYSA-N
InChI
1S/C7H12O2/c8-7(9)6-4-2-1-3-5-6/h6H,1-5H2,(H,8,9)
SMILES string
OC(=O)C1CCCCC1
assay
98%
form
solid
refractive index
n20/D 1.461 (lit.)
bp
232-233 °C (lit.)
mp
29-31 °C (lit.)
solubility
H2O: soluble 0.201g in 100g at 15 °C
organic solvents: soluble
density
1.033 g/mL at 25 °C (lit.)
functional group
carboxylic acid
Quality Level
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Application
环己烷羧酸被用于测定三种天然环糊精与七种环己烷衍生物的复合物结合常数 。
Biochem/physiol Actions
环己烷羧酸在一株厌氧杆菌的作用下发生微生物降解形成对羟基苯甲酸。环己烷羧酸发生芳构化，并在体外大鼠肝脏提取物中转化为马尿酸。环己烷羧酸是合成聚酮类抗生素——磷霉素的起始试剂。
Preparation Note
0.201g 环己烷羧酸溶于 15°C 100g 水中。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Biosynthesis of phoslactomycins: cyclohexanecarboxylic acid as the starter unit.
Sekiyama Y, et al.
Tetrahedron, 59(38), 7465-7471 (2003)
The microbial degradation of cyclohexanecarboxylic acid: a pathway involving aromatization to form p-hydroxybenzoic acid.
Blakley ER.
Canadian Journal of Microbiology, 20(10), 1297-1306 (1974)
A Gadre et al.
Journal of pharmaceutical sciences, 86(2), 236-243 (1997-02-01)
Complex binding constants of the three native cyclodextrins with seven cyclohexane derivatives (all possessing the carboxylic acid group) and with the series C6H5(CH2)nCOOH (n = 0 to 4) were measured in aqueous solution at 25 degrees C by potentiometry and
Aromatization of cyclohexanecarboxylic acid.
B M Babior et al.
The Journal of biological chemistry, 241(16), 3643-3651 (1966-08-25)
Housna Mouttaki et al.
Environmental microbiology, 10(12), 3265-3274 (2008-08-19)
In methanogenic environments, the main fate of benzoate is its oxidization to acetate, H(2) and CO(2) by syntrophic associations of hydrogen-producing benzoate degraders and hydrogen-using methanogens. Here, we report the use of benzoate as an electron acceptor. Pure cultures of
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