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Merck
CN

101915

2,4-二氨基甲苯

98%

别名:

4-甲基间苯二胺, 2,4-二氨基甲苯, 2,4-甲苯二胺, 4-甲基-1,3-苯二胺

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关于此项目

线性分子式:
CH3C6H3(NH2)2
化学文摘社编号:
分子量:
122.17
Beilstein:
2205839
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
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质量水平

方案

98%

表单

solid

沸点

283-285 °C (lit.)

mp

97-99 °C (lit.)

SMILES字符串

Cc1ccc(N)cc1N

InChI

1S/C7H10N2/c1-5-2-3-6(8)4-7(5)9/h2-4H,8-9H2,1H3

InChI key

VOZKAJLKRJDJLL-UHFFFAOYSA-N

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应用

  • 采用UV/H2O2工艺降解合成废水中的2,4-二氨基甲苯:该研究探讨了采用UV/H2O2 工艺降解合成废水中的致癌性2,4-二氨基甲苯,重点关注其改进水处理方法的潜力(J Hosseini, A Shokri, 2017)。
  • 用于2,4 -二硝基甲苯氢化的磁性铁氧体负载钯催化剂的开发:该论文讨论了使用Pd/NiFe2O4催化剂将2,4 -二硝基甲苯高效地氢化为2,4-二氨基甲苯,显示了高产率和工业应用潜力(V Hajdu, M Varga, G Muránszky, G Karacs, 2021)。
  • 苦味酸和2, 3-二氨基甲苯、 2, 4-二氨基甲苯形成的不敏感含能盐(insensitive energetic salt)的合成、表征和能量性能:该论文展示了新含能材料的合成和表征,该材料可能对更安全的炸药和烟火装置的开发很重要(N Şen, H Nazir, N Atҫeken, KS Hope, N Acar, 2020

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Muta. 2 - Repr. 2 - Skin Sens. 1 - STOT RE 2

靶器官

Liver,Kidney

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

320.0 °F - closed cup

闪点(°C)

160 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jeroen A J Vanoirbeek et al.
Toxicological sciences : an official journal of the Society of Toxicology, 109(2), 256-264 (2009-04-01)
Toluene diamine (TDA) is formed when toluene diisocyanate (TDI), a potent sensitizer, comes in contact with an aqueous environment. The sensitizing capacity of TDA and the cross-reactivity between TDI and TDA are unknown. TDA (5-25%) and TDI (0.3%), dissolved in
Tadashi Sakai et al.
International archives of occupational and environmental health, 78(6), 459-466 (2005-05-27)
To develop a simple and sensitive GC-MS method for determining toluene-diamine (TDA) in urine and to apply the method for biological monitoring of workers exposed to toluene-diisocyanate (TDI). After acid hydrolysis of 0.1 ml of urine, diluted tenfold with water
Xiaoyu Wang et al.
Journal of chromatography. A, 1216(43), 7324-7328 (2009-06-16)
A capillary electrophoretic method was explored to assay aromatic amines in food samples. With an inline-coupled transient isotachophoretic stacking approach, the method has yielded about 200-fold improvement of sensitivity in UV detection of three primary aromatic amines and melamine. By
Kazunori Narumi et al.
Mutation research, 747(2), 234-239 (2012-06-09)
Various liver micronucleus assay methods, such as those involving partial hepatectomy, treatment with mitogens, and the use of juvenile animals, have been developed. These assays have been proven to be of high sensitivity and specificity to predict hepatocarcinogenicity of compounds
Isabelle Séverin et al.
Toxicology, 213(1-2), 138-146 (2005-07-06)
2,4-Diaminotoluene (2,4-DAT) is a widely used industrial intermediate and human exposure is possible in the dye and plastics industries. We investigated the genotoxicity of the environmental pollutant, 2,4-DAT, in human HepG2 cells using the unscheduled DNA synthesis (UDS) test, the

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