103543
4-硝基苯甲醚
97%
别名:
1-甲氧基-4-硝基苯
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关于此项目
线性分子式:
O2NC6H4OCH3
化学文摘社编号:
分子量:
153.14
Beilstein:
1865361
EC 号:
MDL编号:
UNSPSC代码:
12352100
eCl@ss:
39032065
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
表单
solid
密度
1.233 g/mL at 25 °C (lit.)
官能团
nitro
SMILES字符串
COc1ccc(cc1)[N+]([O-])=O
InChI
1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3
InChI key
BNUHAJGCKIQFGE-UHFFFAOYSA-N
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一般描述
4-硝基苯甲醚可经过氢氧根离子光化学亲核芳香取代，形成4-甲氧基苯酚和4-硝基苯酚。
应用
使用4-硝基苯甲醚作为探针以确定 Kamlet-Taft溶剂参数Π*，以及在16-420°C温度范围内的高压和超临界水。 4-硝基苯甲醚被用作碳和能量补充剂，以用于分离 红球菌 。
生化/生理作用
4-硝基苯甲醚可被人肝脏微粒体经 O-去甲基化为4-硝基苯酚 。
警示用语：
Warning
危险声明
危险分类
Aquatic Chronic 3 - Carc. 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
闪点(°F)
266.0 °F - closed cup
闪点(°C)
130 °C - closed cup
个人防护装备
Eyeshields, Gloves
法规信息
危险化学品
此项目有
Petr Klán et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(12), 1012-1016 (2003-03-29)
A temperature-sensitive photochemical nucleophilic aromatic substitution on 4-nitroanisole by a hydroxide ion in homogeneous solutions, in a two-phase system under phase-transfer catalysis conditions, and in the microwave field is reported. It was found that reaction regioselectivity dramatically changes with temperature
Vadim Samoilov et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-15)
In this study approaches for chemical conversions of the renewable compounds 1,2-propanediol (1,2-PD) and 2,3-butanediol (2,3-BD) that yield the corresponding cyclic ketals and glycol ethers have been investigated experimentally. The characterization of the obtained products as potential green solvents and
H V Gelboin et al.
Chemical research in toxicology, 9(6), 1023-1030 (1996-09-01)
A panel of 17 hybridomas producing (MAbs) against human cytochrome P450 2E1 (h2E1) was generated by immunizing mice with baculovirus-expressed h2E1. All 17 hybridoma clones gave positive ELISA or immunoblots with either baculovirus-or vaccinia virus-expressed h2E1. Two of the latter
V V Shumyantseva et al.
Biochemistry and molecular biology international, 45(1), 171-179 (1998-06-23)
Semisynthetic flavocytochromes, obtained by covalent binding of riboflavin with cytochromes P450 2B4, were able to catalyze the H2O2-mediated reactions of aniline p-hydroxylation, aminopyrine N-demethylation and p-nitroanizole' O-dealkylation. The rates of the flavocytochrome-catalyzed, H2O2-supported reactions far exceeded those of the appropriate
M S Romero-Cano et al.
Journal of controlled release : official journal of the Controlled Release Society, 82(1), 127-135 (2002-07-11)
The controlled release of 4-nitroanisole from polylactide nanoparticles with different morphologies is reported. Two theoretical equations have been used in an attempt to fit the experimental results. Good agreement between theory and experiment was found for short release time. The
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