103543
4-硝基苯甲醚
97%
别名:
1-甲氧基-4-硝基苯
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关于此项目
线性分子式:
O2NC6H4OCH3
化学文摘社编号:
分子量:
153.14
Beilstein:
1865361
EC 号:
MDL编号:
UNSPSC代码:
12352100
eCl@ss:
39032065
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
表单
solid
密度
1.233 g/mL at 25 °C (lit.)
官能团
nitro
SMILES字符串
COc1ccc(cc1)[N+]([O-])=O
InChI
1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3
InChI key
BNUHAJGCKIQFGE-UHFFFAOYSA-N
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一般描述
4-硝基苯甲醚可经过氢氧根离子光化学亲核芳香取代，形成4-甲氧基苯酚和4-硝基苯酚。
应用
使用4-硝基苯甲醚作为探针以确定 Kamlet-Taft溶剂参数Π*，以及在16-420°C温度范围内的高压和超临界水。 4-硝基苯甲醚被用作碳和能量补充剂，以用于分离 红球菌 。
生化/生理作用
4-硝基苯甲醚可被人肝脏微粒体经 O-去甲基化为4-硝基苯酚 。
警示用语：
Warning
危险声明
危险分类
Aquatic Chronic 3 - Carc. 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
闪点(°F)
266.0 °F - closed cup
闪点(°C)
130 °C - closed cup
个人防护装备
Eyeshields, Gloves
法规信息
危险化学品
此项目有
Petr Klán et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(12), 1012-1016 (2003-03-29)
A temperature-sensitive photochemical nucleophilic aromatic substitution on 4-nitroanisole by a hydroxide ion in homogeneous solutions, in a two-phase system under phase-transfer catalysis conditions, and in the microwave field is reported. It was found that reaction regioselectivity dramatically changes with temperature
D J Sequeira et al.
Biochimica et biophysica acta, 1207(2), 179-186 (1994-08-17)
The goal of this study was to examine the effect of duration of ethylbenzene exposure on cytochrome P-450-dependent activities. Male rats were treated with ethylbenzene by intraperitoneal injection for either 1 or 3 days, and microsomal preparations were examined for
Andrea Ciani et al.
Environmental science & technology, 39(17), 6712-6720 (2005-09-30)
Photodegradation is a key process in governing the residence time and fate of many agrochemicals in top soils. However, the basic knowledge of the photolytic transformation reactions of organic chemicals on soil surfaces is still very poor, particularly regarding the
Andrea Ciani et al.
Chemosphere, 61(10), 1410-1418 (2005-07-12)
The kinetics of direct photochemical transformations of organic compounds in light absorbing and scattering media has been sparsely investigated. This is mostly due to the experimental difficulties to assess the major parameters: light intensity in porous media, the reaction quantum
Kimitaka Minami et al.
Physical chemistry chemical physics : PCCP, 8(19), 2257-2264 (2006-05-12)
Kamlet-Taft solvent parameters, pi*, of high pressure and supercritical water were determined from 16-420 degrees C based on solvatochromic measurements of 4-nitroanisole. For the measurements, an optical cell that could be used at high temperatures and pressures was developed with
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