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103543

4-硝基苯甲醚

97%

别名:

1-甲氧基-4-硝基苯

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关于此项目

线性分子式:
O2NC6H4OCH3
化学文摘社编号:
100-17-4
分子量:
153.14
NACRES:
NA.22
PubChem Substance ID:
24846610
eCl@ss:
39032065
UNSPSC Code:
12352100
EC Number:
202-825-3
MDL number:
MFCD00007327
Beilstein/REAXYS Number:
1865361
Assay:
97%
Form:
solid
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assay

97%

form

solid

density

1.233 g/mL at 25 °C (lit.)

functional group

nitro

SMILES string

COc1ccc(cc1)[N+]([O-])=O

InChI

1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3

InChI key

BNUHAJGCKIQFGE-UHFFFAOYSA-N

General description

4-硝基苯甲醚可经过氢氧根离子光化学亲核芳香取代，形成4-甲氧基苯酚和4-硝基苯酚。

Application

使用4-硝基苯甲醚作为探针以确定 Kamlet-Taft溶剂参数Π*，以及在16-420°C温度范围内的高压和超临界水。 4-硝基苯甲醚被用作碳和能量补充剂，以用于分离 红球菌 。

Biochem/physiol Actions

4-硝基苯甲醚可被人肝脏微粒体经 O-去甲基化为4-硝基苯酚 。

pictograms

Health hazard
GHS08

signalword

Warning

hcodes

H351,H412

Hazard Classifications

Aquatic Chronic 3 - Carc. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

266.0 °F - closed cup

flash_point_c

130 °C - closed cup

ppe

Eyeshields, Gloves

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBF7314V
STBF4722V
STBD0772V
STBC8738V
STBC7426V

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Petr Klán et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(12), 1012-1016 (2003-03-29)
A temperature-sensitive photochemical nucleophilic aromatic substitution on 4-nitroanisole by a hydroxide ion in homogeneous solutions, in a two-phase system under phase-transfer catalysis conditions, and in the microwave field is reported. It was found that reaction regioselectivity dramatically changes with temperature
Kimitaka Minami et al.
Physical chemistry chemical physics : PCCP, 8(19), 2257-2264 (2006-05-12)
Kamlet-Taft solvent parameters, pi*, of high pressure and supercritical water were determined from 16-420 degrees C based on solvatochromic measurements of 4-nitroanisole. For the measurements, an optical cell that could be used at high temperatures and pressures was developed with
Andrea Ciani et al.
Environmental science & technology, 39(17), 6712-6720 (2005-09-30)
Photodegradation is a key process in governing the residence time and fate of many agrochemicals in top soils. However, the basic knowledge of the photolytic transformation reactions of organic chemicals on soil surfaces is still very poor, particularly regarding the
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全球贸易项目编号

货号GTIN
103543-25G04061838670601
103543-5G04061838670618