104914
二氯甲基乙烯基硅烷
97%
别名:
甲基乙烯基二氯硅烷
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关于此项目
线性分子式:
H2C=CHSi(CH3)Cl2
化学文摘社编号:
分子量:
141.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-710-3
Beilstein/REAXYS Number:
1740822
MDL number:
产品名称
二氯甲基乙烯基硅烷, 97%
InChI key
YLJJAVFOBDSYAN-UHFFFAOYSA-N
InChI
1S/C3H6Cl2Si/c1-3-6(2,4)5/h3H,1H2,2H3
SMILES string
C[Si](Cl)(Cl)C=C
vapor density
>1 (vs air)
assay
97%
refractive index
n20/D 1.430 (lit.)
bp
92 °C (lit.)
density
1.08 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
Dichloromethylvinylsilane was used as single molecular precursor for the deposition of β-SiC thin films and β -SiC nanowires by metalorganic chemical vapor deposition on bare Si 100 and Ni-coated Si 100 substrates. Dichloromethylvinylsilane was used in the synthesis and characterization of Tris(1-(dichloro(methyl)silyl)ethyl)borane,monomer.
General description
Dichloromethylvinylsilane reacts with dimethylsulphide borane to form organosilylborane, which further gets ammonolysized to form the polymer of the SiBCN.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2 - Skin Corr. 1B
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
38.1 °F - closed cup
flash_point_c
3.4 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Influence of the Precursor Cross-Linking Route on the Thermal Stability of Si- B- C- O Ceramics.
Ischenko V, et al.
Chemistry of Materials, 20(22), 7148-7156 (2008)
Growth of β-SiC nanowires and thin films by metalorganic chemical vapor deposition using dichloromethylvinylsilane.
Kang B-C, et al.
J. Vac. Sci. Technol. B, 23(4), 1722-1725 (2005)
Synthesis and Structure Characterization of Amorphous SiBCN Ceramic Precursors.
Yajing L and Yue Z.
Rare Metals Materials and Engineering, 40, 234-237 (2011)
H Yamakita et al.
Radioisotopes, 33(8), 513-518 (1984-08-01)
Poly(methylvinylsiloxane)-bonded silica gel was synthesized by condensation reaction between silica gel and the hydrolysis product of methylvinyldichlorosilane. Graft polymerization of styrene or indene onto poly(methylvinylsiloxane)-bonded silica gel was carried out by gamma-ray irradiation and compared with that onto silica gel.
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