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Merck
CN

104914

二氯甲基乙烯基硅烷

97%

别名:

甲基乙烯基二氯硅烷

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关于此项目

线性分子式:
H2C=CHSi(CH3)Cl2
化学文摘社编号:
分子量:
141.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-710-3
Beilstein/REAXYS Number:
1740822
MDL number:
Assay:
97%
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InChI key

YLJJAVFOBDSYAN-UHFFFAOYSA-N

InChI

1S/C3H6Cl2Si/c1-3-6(2,4)5/h3H,1H2,2H3

SMILES string

C[Si](Cl)(Cl)C=C

vapor density

>1 (vs air)

assay

97%

Quality Level

bp

92 °C (lit.)

density

1.08 g/mL at 25 °C (lit.)

storage temp.

2-8°C

General description

Dichloromethylvinylsilane reacts with dimethylsulphide borane to form organosilylborane, which further gets ammonolysized to form the polymer of the SiBCN.

Application

Dichloromethylvinylsilane was used as single molecular precursor for the deposition of β-SiC thin films and β -SiC nanowires by metalorganic chemical vapor deposition on bare Si 100 and Ni-coated Si 100 substrates. Dichloromethylvinylsilane was used in the synthesis and characterization of Tris(1-(dichloro(methyl)silyl)ethyl)borane,monomer.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2 - Skin Corr. 1B

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

38.1 °F - closed cup

flash_point_c

3.4 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and Structure Characterization of Amorphous SiBCN Ceramic Precursors.
Yajing L and Yue Z.
Rare Metals Materials and Engineering, 40, 234-237 (2011)
Growth of β-SiC nanowires and thin films by metalorganic chemical vapor deposition using dichloromethylvinylsilane.
Kang B-C, et al.
J. Vac. Sci. Technol. B, 23(4), 1722-1725 (2005)
Influence of the Precursor Cross-Linking Route on the Thermal Stability of Si- B- C- O Ceramics.
Ischenko V, et al.
Chemistry of Materials, 20(22), 7148-7156 (2008)
H Yamakita et al.
Radioisotopes, 33(8), 513-518 (1984-08-01)
Poly(methylvinylsiloxane)-bonded silica gel was synthesized by condensation reaction between silica gel and the hydrolysis product of methylvinyldichlorosilane. Graft polymerization of styrene or indene onto poly(methylvinylsiloxane)-bonded silica gel was carried out by gamma-ray irradiation and compared with that onto silica gel.

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