Merck
CN
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文件

105228

Sigma-Aldrich

1,1,1,3,3,3-六氟-2-丙醇

≥99%

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别名:
HFP, 六氟异丙醇
线性分子式:
(CF3)2CHOH
CAS号:
920-66-1
分子量:
168.04
Beilstein:
1841007
EC 号:
213-059-4
MDL编号:
MFCD00011651
PubChem化学物质编号:
24846695
NACRES:
NA.22

质量水平

200

检测方案

≥99%

折射率

n20/D 1.275 (lit.)

bp

59 °C (lit.)

mp

−4 °C (lit.)

密度

1.596 g/mL at 25 °C (lit.)

SMILES string

OC(C(F)(F)F)C(F)(F)F

InChI

1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H

InChI key

BYEAHWXPCBROCE-UHFFFAOYSA-N

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相关类别

一般描述

1,1,1,3,3,3-六氟-2-丙醇是溶液相肽化学溶剂。这种高电离能力的氟化极性溶剂可在无路易斯酸催化剂的情况下，通过共价试剂促进傅-克烷基化反应。它还可提高铑(I)催化的醚键连接的炔基二烯的[4 + 2]分子内环加成反应，以及炔基乙烯基环丙烷的[5 + 2]环加成反应效率。1,1,1,3,3,3-六氟-2-丙醇结合过氧化氢可团簇催化环辛烯和1-辛烯的环氧化作用。

应用

1,1,1,3,3,3-六氟-2-丙醇可用于制备六氟醇官能化甲基丙烯酸酯聚合物。

象形图

CorrosionHealth hazard
GHS05,GHS08

警示用语：

Danger

危险声明

H314 - H361 - H373

危险分类

Eye Dam. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2

储存分类代码

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 2

闪点(°F)

No data available

闪点(°C)

No data available

个人防护装备

Faceshields, Gloves, Goggles

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索取COA

  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. What is Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol, soluble in?

    According to literature, 1,1,1,3,3,3-Hexafluoro-2-propanol is soluble in 100% ethanol (to 10% v/v), which will yield colorless solution, chloroform, and water.

  4. What is the vapor pressure of Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol?

    The vapor pressure of this product has been reported as 42.1 mbar at 0 degrees C.

  5. How should Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol, be stored?

    1,1,1,3,3,3-Hexafluoro-2-propanol should be stored in a cooler prior to opening since this product evaporates quickly and this will relieve pressure within the bottle.

  6. Can Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol, be used as a solution phase peptide chemistry solvent?

    This product is a solution phase peptide chemistry solvent an that applications has been cited in literature.  A specific reference would be:  Biochem. 29, 2639 (1990).

  7. What type of gloves should be worn while handling Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol?

    We would recommend using neoprene gloves while handling this compound.

  8. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  9. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  10. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Rita Sobreiro-Almeida et al.
Materials science & engineering. C, Materials for biological applications, 103, 109866-109866 (2019-07-28)
Kidney diseases are recognized as a major health problem, which affect 10% of the population. Because currently available therapies have many limitations, some tissue engineering strategies have been emerging as promising approaches in this field. In this work, porcine kidneys
Kinetic Studies of Olefin Epoxidation with Hydrogen Peroxide in 1, 1, 1, 3, 3, 3-Hexafluoro-2-propanol Reveal a Crucial Catalytic Role for Solvent Clusters.
Berkessel A and Adrio JA.
Advanced Synthesis & Catalysis, 346(2-3), 275-280 (2004)
Hexafluoroalcohol-functionalized Methacrylate Monomers for Lithographic/Nanopatterning Materials.
Sanders DP, et al.
Material Matters, 6(1), 1-7 (2011)
Akio Saito et al.
The Journal of organic chemistry, 71(17), 6437-6443 (2006-08-12)
In fluorinated alcohols, the cationic Rh(I) species, which is derived from [Rh(COD)Cl]2 and AgSbF6, efficiently catalyzed intramolecular [4+2] cycloaddition reactions of ester-tethered 1,3-diene-8-yne derivatives. The catalytic system was also effective in intramolecular [5+2] cycloaddition reactions of ester-tethered omega-alkynyl vinylcyclopropane compounds.
Lewis acid catalyst free electrophilic alkylation of silicon-capped pi donors in 1,1,1,3,3,3-hexafluoro-2-propanol.
Maxim O Ratnikov et al.
Angewandte Chemie (International ed. in English), 47(50), 9739-9742 (2008-11-05)
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