106224
3-溴噻吩
97%
别名:
3-噻吩基溴
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关于此项目
经验公式（希尔记法）:
C4H3BrS
化学文摘社编号:
分子量:
163.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-821-3
Beilstein/REAXYS Number:
105338
MDL number:
Assay:
97%
Quality Level
assay
97%
refractive index
n20/D 1.591 (lit.)
bp
150 °C (lit.)
density
1.74 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
Brc1ccsc1
InChI
1S/C4H3BrS/c5-4-1-2-6-3-4/h1-3H
InChI key
XCMISAPCWHTVNG-UHFFFAOYSA-N
Application
3-溴噻吩可用作合成以下物质的反应物：
- 通过硼化作用和之后的Suzuki偶联反应生成3,3-双噻吩。
- 通过NiDPPP++催化的与格氏试剂的交叉偶联反应生成3-烷基噻吩。
- 以 n-丁基锂在己烷中处理生成3-噻吩基锂。
- 带噻吩基的αω−二甲酰基−α−寡聚噻吩的衍生物。
- 在碘苯二乙酸(178721)的介导下，通过在2-位置与N-芳基甲磺酰胺的偶联作用生成N-(2-(3-溴噻吩-2-基)苯基)甲磺酰胺。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
125.6 °F - closed cup
flash_point_c
52 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Cyclopalladated ferrocenylimine: a highly effective catalyst for the borylation/suzuki coupling reaction
Ning Ma, et al.
Tetrahedron, 63, 4625-4625 (2007)
Room temperature stable 3-lithiothiophene: a facile synthesis of 3-functional thiophenes.
Wu X, et al.
Tetrahedron Letters, 35(22), 3673-3674 (1994)
M Zangoli et al.
Nanoscale, 9(26), 9202-9209 (2017-06-27)
We report that nanoparticles prepared from appropriately functionalized polythiophenes once administered to live cells can acquire phototransduction properties under illumination, becoming photoactive sites able to absorb visible light and convert it to an electrical signal through cell membrane polarization. Amine-reactive
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 106224-100G | 04061838673879 |
| 106224-5G | 04061838673893 |
| 106224-25G | 04061838673886 |