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线性分子式:
CH2=C(CH3)CH2Cl
化学文摘社编号:
分子量:
90.55
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39050134
UNSPSC Code:
12352100
EC Number:
209-251-2
MDL number:
Beilstein/REAXYS Number:
878160
Assay:
90%
产品名称
3-氯-2-甲基-1-丙烯, technical grade, 90%
InChI key
OHXAOPZTJOUYKM-UHFFFAOYSA-N
InChI
1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3
SMILES string
CC(=C)CCl
grade
technical grade
vapor density
3.12 (vs air)
vapor pressure
102 mmHg ( 20 °C)
assay
90%
autoignition temp.
899 °F
contains
~600 ppm BHT as stabilizer
expl. lim.
9.3 %
refractive index
n20/D 1.427 (lit.)
bp
71-72 °C (lit.)
mp
−80 °C (lit.)
solubility
H2O: insoluble
acetone: soluble
chloroform: soluble
diethyl ether: soluble
ethanol: soluble
density
0.925 g/mL at 20 °C (lit.)
functional group
alkyl halide
chloro
storage temp.
2-8°C
Quality Level
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Application
3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.
General description
3-Chloro-2-methyl-1-propene is the reactant for the synthesis of cyclobutanone.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Cyclobutanone from Methylenecyclopropane via Oxaspiropentane.
Salaun JRJC and Conia JM.
Organic Syntheses, 36-36 (1977)
The cationic polymerization of 3-chloro-2-methyl-1-propene.
Marek M, et al.
Makromol. Chem., 187(10), 2337-2344 (1986)
3-Chloro-2-methylpropene.
Report on carcinogens : carcinogen profiles, 10, 57-58 (2004-08-24)
3-Chloro-2-methylpropene.
IARC monographs on the evaluation of carcinogenic risks to humans, 63, 325-333 (1995-01-01)
P C Chan et al.
Cancer research, 46(12 Pt 1), 6349-6352 (1986-12-01)
The carcinogenicity of 3-chloro-2-methylpropene (CMP), a chemical intermediate and insecticide, was studied because of possible human exposure and because of its structural relationship to vinyl chloride and allyl chloride. CMP in corn oil was administered by gavage to groups of
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