Merck
CN

108030

Sigma-Aldrich

3-氯-2-甲基-1-丙烯

technical grade, 90%

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别名:
β-甲基烯丙基氯
线性分子式:
CH2=C(CH3)CH2Cl
CAS号:
分子量:
90.55
Beilstein:
878160
EC 号:
MDL编号:
eCl@ss:
39050134
PubChem化学物质编号:

等级

technical grade

质量水平

蒸汽密度

3.12 (vs air)

蒸汽压

102 mmHg ( 20 °C)

检测方案

90%

自燃温度

899 °F

包含

~600 ppm BHT as stabilizer

expl. lim.

9.3 %

折射率

n20/D 1.427 (lit.)

bp

71-72 °C (lit.)

mp

−80 °C (lit.)

溶解性

H2O: insoluble
acetone: soluble
chloroform: soluble
diethyl ether: soluble
ethanol: soluble

密度

0.925 g/mL at 20 °C (lit.)

储存温度

2-8°C

SMILES string

CC(=C)CCl

InChI

1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3

InChI key

OHXAOPZTJOUYKM-UHFFFAOYSA-N

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一般描述

3-Chloro-2-methyl-1-propene is the reactant for the synthesis of cyclobutanone.

应用

3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

14.0 °F - closed cup

闪点(°C)

-10 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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The cationic polymerization of 3-chloro-2-methyl-1-propene.
Marek M, et al.
Makromol. Chem., 187(10), 2337-2344 (1986)
Cyclobutanone from Methylenecyclopropane via Oxaspiropentane.
Salaun JRJC and Conia JM.
Organic Syntheses, 36-36 (1977)
K Hooper et al.
American journal of industrial medicine, 22(6), 793-808 (1992-01-01)
In California, 370 carcinogens and 112 reproductive/developmental toxicants have been identified as a result of the State's Safe Drinking Water and Toxic Enforcement Act of 1986. They include pesticides, solvents, metals, industrial intermediates, environmental mixtures, and reactive agents. Occupational, environmental
Ring-opening polymerization of various oxirane derivatives using organotin phosphate condensate; selective synthesis of the polyether containing oxirane ring in the side chain.
Iwasa N, et al.
Polym. Bull., 61(2), 207-216 (2008)
T Katagiri et al.
Industrial health, 38(3), 309-318 (2000-08-16)
Chronic toxicity and carcinogenicity studies of 3-chloro-2-methylpropene (CMP), which has been widely used as an insecticide and chemical intermediate, were carried out in BDF1 mice. CMP was administered to mice in groups of 50 male and 50 female mice by

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