108030
3-氯-2-甲基-1-丙烯
technical grade, 90%
别名:
β-甲基烯丙基氯
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关于此项目
线性分子式:
CH2=C(CH3)CH2Cl
化学文摘社编号:
分子量:
90.55
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39050134
UNSPSC Code:
12352100
EC Number:
209-251-2
MDL number:
Beilstein/REAXYS Number:
878160
产品名称
3-氯-2-甲基-1-丙烯, technical grade, 90%
InChI key
OHXAOPZTJOUYKM-UHFFFAOYSA-N
InChI
1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3
SMILES string
CC(=C)CCl
grade
technical grade
vapor density
3.12 (vs air)
vapor pressure
102 mmHg ( 20 °C)
assay
90%
autoignition temp.
899 °F
contains
~600 ppm BHT as stabilizer
expl. lim.
9.3 %
refractive index
n20/D 1.427 (lit.)
bp
71-72 °C (lit.)
mp
−80 °C (lit.)
solubility
H2O: insoluble
acetone: soluble
chloroform: soluble
diethyl ether: soluble
ethanol: soluble
density
0.925 g/mL at 20 °C (lit.)
functional group
alkyl halide
chloro
storage temp.
2-8°C
Quality Level
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Application
3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.
General description
3-Chloro-2-methyl-1-propene is the reactant for the synthesis of cyclobutanone.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Cyclobutanone from Methylenecyclopropane via Oxaspiropentane.
Salaun JRJC and Conia JM.
Organic Syntheses, 36-36 (1977)
The cationic polymerization of 3-chloro-2-methyl-1-propene.
Marek M, et al.
Makromol. Chem., 187(10), 2337-2344 (1986)
K Hooper et al.
American journal of industrial medicine, 22(6), 793-808 (1992-01-01)
In California, 370 carcinogens and 112 reproductive/developmental toxicants have been identified as a result of the State's Safe Drinking Water and Toxic Enforcement Act of 1986. They include pesticides, solvents, metals, industrial intermediates, environmental mixtures, and reactive agents. Occupational, environmental
Ring-opening polymerization of various oxirane derivatives using organotin phosphate condensate; selective synthesis of the polyether containing oxirane ring in the side chain.
Iwasa N, et al.
Polym. Bull., 61(2), 207-216 (2008)
3-Chloro-2-methylpropene.
Report on carcinogens : carcinogen profiles, 10, 57-58 (2004-08-24)
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