蒸汽压
0.04 mmHg ( 20 °C)
质量水平
方案
96%
折射率
n20/D 1.551 (lit.)
沸点
251-252 °C (lit.)
mp
13-15 °C (lit.)
溶解性
alcohol: soluble
cold water: insoluble
diethyl ether: soluble
密度
1.384 g/mL at 25 °C (lit.)
SMILES字符串
ClS(=O)(=O)c1ccccc1
InChI
1S/C6H5ClO2S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
InChI key
CSKNSYBAZOQPLR-UHFFFAOYSA-N
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一般描述
Benzenesulfonyl chloride reacts with Grignard reagent from N-unsubstituted indoles to form oxindoles or substituted indoles. It is the derivatization reagent for the determination of various amines in waste water and surface water at the sub-ppb level by gas chromatography-mass spectrometry.
应用
Benzenesulfonyl chloride may be used in thiamine assay for determination of thiamine in different food products.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 1
闪点(°F)
260.6 °F
闪点(°C)
127 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Analysis of primary and secondary aliphatic amines in waste water and surface water by gas chromatography-mass spectrometry after derivatization with 2, 4-dinitrofluorobenzene or benzenesulfonyl chloride.
Sacher F, et al.
Journal of Chromatography A, 764(1), 85-93 (1997)
Unusual reactions of magnesium indolates with benzenesulfonyl chloride.
Wenkert E, et al.
The Journal of Organic Chemistry, 52(15), 3404-3409 (1987)
A G Soliman
Journal - Association of Official Analytical Chemists, 64(3), 616-622 (1981-05-01)
A semiautomated procedure was used to measure the fluorescence of sample extracts before and after the addition of benzenesulfonyl chloride (BSC). Addition of BSC inhibited thiochrome formation and provided a more representative blank based on the fluorescence of all the
H Kataoka et al.
Biomedical chromatography : BMC, 6(5), 251-254 (1992-09-01)
A selective and sensitive method for the determination of low molecular weight aliphatic primary amines in urine is described. These amines were converted into their benzenesulphonyl derivatives by a modified Hinsberg procedure, and measured by gas chromatography with flame photometric
Mario O Salazar et al.
Molecular diversity, 15(3), 713-719 (2011-01-06)
A semisynthetic β-glucosidase inhibitor was identified from a chemically engineered extract prepared by reaction with benzenesulfonyl chloride. The structure includes a natural histamine portion and a benzenesulfonyl portion introduced during the diversification step.
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