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10894

六氯-2-丙酮

Name: 六氯-2-丙酮
Brand: ALDRICH

Wacker Chemie AG, ≥99.0% (GC)

别名:

HCA, 六氯丙酮

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关于此项目

线性分子式:

CCl₃COCCl₃

化学文摘社编号:

116-16-5

分子量:

264.75

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57646830

EC Number:

204-129-5

Beilstein/REAXYS Number:

1707475

MDL number:

MFCD00000796

Assay:

≥99.0% (GC)

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属性

Quality Level

100

assay

≥99.0% (GC)

manufacturer/tradename

Wacker Chemie AG

refractive index

n20/D 1.511 (lit.)

bp

66-70 °C/6 mmHg (lit.)

mp

−6-−2 °C (lit.)

density

1.743 g/mL at 25 °C (lit.)

application(s)

agriculture
environmental

functional group

chloro, ketone

SMILES string

ClC(Cl)(Cl)C(=O)C(Cl)(Cl)Cl

InChI

1S/C3Cl6O/c4-2(5,6)1(10)3(7,8)9

InChI key

DOJXGHGHTWFZHK-UHFFFAOYSA-N

说明

General description

Hexachloro-2-propanone is a colorless liquid. It is present in herbicide Bromacil formulation. Hexachloro-2-propanone is precursor for the generation and cycloaddition of oxyallyl intermediates. It reverts the Ames strains TA98 and TA100 but not the non-plasmid strains TA1537, TA1535 and TA1538.

Application

Hexachloro-2-propanone (hexachloroacetone) was used in the synthesis of chirally deuterated benzyl chlorides and enol phosphate 2,2-dichloro-1-(trichloromethyl)ethenyl diethyl phosphate. It was also used in obtaining efficient amino acid activation by exploiting the rapid formation of acid chlorides under low temperature and acid/base free conditions.

Other Notes

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pictograms

GHS06,GHS09

signalword

Danger

hcodes

H302,H317,H331,H411

pcodes

P261 - P273 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

农药列管产品

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Chirally deuterated benzyl chlorides from benzyl alcohols via hexachloroacetone/polymer-supported triphenylphosphine: synthesis of protected (2S, 3S)-[3-(2)H, (15)N]-tyrosine.

Derek W Barnett et al.

Journal of labelled compounds & radiopharmaceuticals, 56(1), 6-11 (2013-11-29)

Chirally deuterated benzyl chlorides were prepared using novel, general hexachloroacetone/polymer-supported triphenylphosphine treatment of chirally deuterated benzyl alcohols. Doubly labeled protected tyrosine was obtained in 62% yield with 86% de at the α-carbon and 82% de at the β-carbon. Key in

The mutagenic properties of hexachloroacetone in short-term bacterial mutagen assay systems.

H Zochlinski et al.

Mutation research, 89(2), 137-144 (1981-06-01)

Hexachloroacetone, CCl3--CO--CCl3, reverts the Ames strains TA98 and TA100 but not the non-plasmid strains TA1537, TA1535 and TA1538. In the absence of solvent, the number of revertant colonies is 5 times the spontaneous reversion rate for TA100 and 10 times

Determination of hexachloroacetone in air.

E Kissa

Analytical chemistry, 55(8), 1222-1225 (1983-07-01)

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341010-25G	04061826753514
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