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线性分子式:
HSCH2CO2CH3
化学文摘社编号:
分子量:
106.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-121-7
Beilstein/REAXYS Number:
506259
MDL number:
产品名称
巯基乙酸甲酯, 95%
InChI key
MKIJJIMOAABWGF-UHFFFAOYSA-N
InChI
1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3
SMILES string
COC(=O)CS
assay
95%
reaction suitability
reagent type: ligand
reaction type: [1,2]-Wittig Rearrangement
refractive index
n20/D 1.466 (lit.)
bp
42-43 °C/10 mmHg (lit.)
density
1.187 g/mL at 25 °C (lit.)
functional group
ester
thiol
Quality Level
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Application
巯基乙酸甲酯用于制备:
光氧化还原催化下C–H键有机催化活化的一般策略:苄基醚的直接芳基化
产品适配我们的光反应器系列:包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
- 3-甲氧羰基-4-氧四氢硫代吡喃, 2-和4-甲氧羰基-3-氧四氢噻吩
- 巯基乙酸甲酯和氨基乙硫醇修饰的金纳米棒。
光氧化还原催化下C–H键有机催化活化的一般策略:苄基醚的直接芳基化
产品适配我们的光反应器系列:包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
General description
巯基乙酸甲酯与抗肿瘤抗生素新抑癌蛋白的非蛋白成分反应形成 1:1 加合物 。它与异硫氰酸盐反应生成罗丹宁 。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
132.8 °F - closed cup
flash_point_c
56 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
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Liu HJ and Ngooi TK.
Canadian Journal of Chemistry, 60(4), 437-439 (1982)
T Kusakabe et al.
Biochemistry, 34(31), 9944-9950 (1995-08-08)
A double-stranded DNA cleavage mechanism by a novel enediyne type antitumor antibiotic, dynemicin A, has been investigated through sequence-dependent strand breakage of a series of duplexes containing a single nucleotide gap. We found that (1) dynemicin A breaks specifically at
Stereochemical assignment of neocarzinostatin chromophore. Structures of neocarzinostatin chromophore-methyl thioglycolate adducts.
Myers AG, et al.
Journal of the American Chemical Society, 110(21), 7212-7214 (1988)
O D Hensens et al.
The Journal of antibiotics, 42(5), 761-768 (1989-05-01)
The structures of mercaptan and sodium borohydride reaction products of neocarzinostatin chromophore A (NCS Chrom A) are compared. Implications on the mechanism of activation of NCS are discussed.
Z Mester et al.
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A gas chromatography/mass spectrometry (GC/MS) method has been developed to determine two methylated arsenic species in human urine samples. The yield of derivatization for dimethylarsinic acid (DMA) and monomethylarsonic acid (MMA) using thioglycol methylate (TGM) was measured. The detection limit
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