108995
巯基乙酸甲酯
95%
别名:
硫代乙醇酸甲酯
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关于此项目
线性分子式:
HSCH2CO2CH3
化学文摘社编号:
分子量:
106.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-121-7
Beilstein/REAXYS Number:
506259
MDL number:
Assay:
95%
InChI key
MKIJJIMOAABWGF-UHFFFAOYSA-N
InChI
1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3
SMILES string
COC(=O)CS
assay
95%
reaction suitability
reagent type: ligand
reaction type: [1,2]-Wittig Rearrangement
Quality Level
bp
42-43 °C/10 mmHg (lit.)
density
1.187 g/mL at 25 °C (lit.)
functional group
ester, thiol
General description
巯基乙酸甲酯与抗肿瘤抗生素新抑癌蛋白的非蛋白成分反应形成 1:1 加合物 。它与异硫氰酸盐反应生成罗丹宁 。
Application
巯基乙酸甲酯用于制备：
光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化
产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
- 3-甲氧羰基-4-氧四氢硫代吡喃, 2-和4-甲氧羰基-3-氧四氢噻吩
- 巯基乙酸甲酯和氨基乙硫醇修饰的金纳米棒。
光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化
产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
132.8 °F - closed cup
flash_point_c
56 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
T Kusakabe et al.
Biochemistry, 34(31), 9944-9950 (1995-08-08)
A double-stranded DNA cleavage mechanism by a novel enediyne type antitumor antibiotic, dynemicin A, has been investigated through sequence-dependent strand breakage of a series of duplexes containing a single nucleotide gap. We found that (1) dynemicin A breaks specifically at
Photodegradation of methyl thioglycolate particles as a proxy for organosulphur containing droplets.
Samantha Seng et al.
Physical chemistry chemical physics : PCCP, 20(29), 19416-19423 (2018-06-28)
Understanding the formation and transformation of sulphur-rich particles is of prime importance since they contribute to the global atmospheric sulphur budget. In this work, we performed a series of experiments on a photoactive organosulphur compound namely, methyl thioglycolate, as a
An improved procedure for the preparation of 3-carbometfaoxy-4-oxotetrahydrothiopyran, 2-and 4-carbomethoxy-3-oxotetrahydrothiophene.
Liu HJ and Ngooi TK.
Canadian Journal of Chemistry, 60(4), 437-439 (1982)
M K Vadnere et al.
Journal of medicinal chemistry, 29(9), 1714-1720 (1986-09-01)
The reaction of methyl mercaptoacetate (5) with phenyl-p-benzoquinone (6) or 5-p-benzoquinonyl-3',5'-di-O-acetyl-2'-deoxyuridine (10) resulted in the formation of the three possible adducts to the quinone rings of 6 and 10; an additional product in the reaction with 10 was the unsubstituted
Y Sugiura et al.
Biochemistry, 30(12), 2989-2992 (1991-03-26)
The reaction products of methyl thioglycolate with dynemicin A, dynemicin H and dynemicin S, were isolated by HPLC purification and identified spectroscopically. The major product, dynemicin H (C30H23NO9), was determined to be a C-8 hydrogen analogue of dynemicins L and
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