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108995

巯基乙酸甲酯

95%

别名:

硫代乙醇酸甲酯

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关于此项目

线性分子式:
HSCH2CO2CH3
化学文摘社编号:
2365-48-2
分子量:
106.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24846848
EC Number:
219-121-7
Beilstein/REAXYS Number:
506259
MDL number:
MFCD00004873
Assay:
95%
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Quality Level

200

assay

95%

reaction suitability

reagent type: ligand
reaction type: [1,2]-Wittig Rearrangement

refractive index

n20/D 1.466 (lit.)

bp

42-43 °C/10 mmHg (lit.)

density

1.187 g/mL at 25 °C (lit.)

functional group

ester, thiol

SMILES string

COC(=O)CS

InChI

1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3

InChI key

MKIJJIMOAABWGF-UHFFFAOYSA-N

General description

巯基乙酸甲酯与抗肿瘤抗生素新抑癌蛋白的非蛋白成分反应形成 1:1 加合物 。它与异硫氰酸盐反应生成罗丹宁 。

Application

巯基乙酸甲酯用于制备：
  • 3-甲氧羰基-4-氧四氢硫代吡喃, 2-和4-甲氧羰基-3-氧四氢噻吩
  • 巯基乙酸甲酯和氨基乙硫醇修饰的金纳米棒。
制备硫醇有机催化剂用于通过可见光催化影响苄基醚C-H键的直接芳基化

光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化

产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

132.8 °F - closed cup

flash_point_c

56 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB6226
STBK4119
STBJ5810
BCBC0358
STBD9917V

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M K Vadnere et al.
Journal of medicinal chemistry, 29(9), 1714-1720 (1986-09-01)
The reaction of methyl mercaptoacetate (5) with phenyl-p-benzoquinone (6) or 5-p-benzoquinonyl-3',5'-di-O-acetyl-2'-deoxyuridine (10) resulted in the formation of the three possible adducts to the quinone rings of 6 and 10; an additional product in the reaction with 10 was the unsubstituted
Yuling Xiao et al.
Theranostics, 2(8), 757-768 (2012-08-24)
A multifunctional gold nanorod (GNR)-based nanoplatform for targeted anticancer drug delivery and positron emission tomography (PET) imaging of tumors was developed and characterized. An anti-cancer drug (i.e., doxorubicin (DOX)) was covalently conjugated onto PEGylated (PEG: polyethylene glycol) GNR nanocarriers via
O D Hensens et al.
The Journal of antibiotics, 42(5), 761-768 (1989-05-01)
The structures of mercaptan and sodium borohydride reaction products of neocarzinostatin chromophore A (NCS Chrom A) are compared. Implications on the mechanism of activation of NCS are discussed.
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全球贸易项目编号

货号GTIN
108995-500G04061838687760
108995-100G04061838687753
108995-5G04061837245787