一般描述
巯基乙酸甲酯与抗肿瘤抗生素新抑癌蛋白的非蛋白成分反应形成 1:1 加合物 。它与异硫氰酸盐反应生成罗丹宁 。
应用
巯基乙酸甲酯用于制备：
光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化
产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
- 3-甲氧羰基-4-氧四氢硫代吡喃, 2-和4-甲氧羰基-3-氧四氢噻吩
- 巯基乙酸甲酯和氨基乙硫醇修饰的金纳米棒。
光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化
产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
132.8 °F - closed cup
闪点(°C)
56 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
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A double-stranded DNA cleavage mechanism by a novel enediyne type antitumor antibiotic, dynemicin A, has been investigated through sequence-dependent strand breakage of a series of duplexes containing a single nucleotide gap. We found that (1) dynemicin A breaks specifically at
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The reaction of methyl mercaptoacetate (5) with phenyl-p-benzoquinone (6) or 5-p-benzoquinonyl-3',5'-di-O-acetyl-2'-deoxyuridine (10) resulted in the formation of the three possible adducts to the quinone rings of 6 and 10; an additional product in the reaction with 10 was the unsubstituted
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