10904
3-氯-2-丁酮
Wacker Chemie AG, ≥96.0% (GC)
别名:
氯-MEK
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线性分子式:
CH3CHClCOCH3
化学文摘社编号:
分子量:
106.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-834-9
Beilstein/REAXYS Number:
385637
MDL number:
产品名称
3-氯-2-丁酮, Wacker Chemie AG, ≥96.0% (GC)
InChI key
OIMRLHCSLQUXLL-UHFFFAOYSA-N
InChI
1S/C4H7ClO/c1-3(5)4(2)6/h3H,1-2H3
SMILES string
CC(Cl)C(C)=O
assay
≥96.0% (GC)
manufacturer/tradename
Wacker Chemie AG
refractive index
n20/D 1.421 (lit.)
bp
114-117 °C (lit.)
density
1.055 g/mL at 25 °C (lit.)
Quality Level
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Other Notes
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Application
3-Chloro-2-butanone was used to study various carbonylic compounds as substrates for 4-hydroxyacetophenone monooxygenase from Pseudomonas fluorescens ACB.
General description
3-Chloro-2-butanone when treated with aq. sodium thiocyanate forms 3-thiocyano-2-butanone.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
82.4 °F - closed cup
flash_point_c
28 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Reactions of 3-Thiocyano-2-butanone. I. The Preparation of 2-Substituted-4, 5-dimethylthiazoles.
Gregory JT and Mathes RA.
Journal of the American Chemical Society, 74(7), 1719-1720 (1952)
Nanne M Kamerbeek et al.
Applied and environmental microbiology, 69(1), 419-426 (2003-01-07)
The 4-hydroxyacetophenone monooxygenase (HAPMO) from Pseudomonas fluorescens ACB catalyzes NADPH- and oxygen-dependent Baeyer-Villiger oxidation of 4-hydroxyacetophenone to the corresponding acetate ester. Using the purified enzyme from recombinant Escherichia coli, we found that a broad range of carbonylic compounds that are
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