10913
乙酰乙酸甲酯
Wacker Chemie AG, ≥99.0% (GC)
别名:
ACM, 3-丁酮酸甲酯, 乙酰醋酸甲酯
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关于此项目
线性分子式:
CH3COCH2COOCH3
化学文摘社编号:
分子量:
116.12
EC Number:
203-299-8
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
506727
MDL number:
Assay:
≥99.0% (GC)
assay
≥99.0% (GC)
autoignition temp.
536 °F
manufacturer/tradename
Wacker Chemie AG
refractive index
n20/D 1.419 (lit.)
bp
169-170 °C/70 mmHg (lit.)
mp
−80 °C (lit.)
solubility
H2O: soluble 2 parts, alcohol: miscible, diethyl ether: miscible
density
1.076 g/mL at 25 °C (lit.)
SMILES string
COC(=O)CC(C)=O
InChI
1S/C5H8O3/c1-4(6)3-5(7)8-2/h3H2,1-2H3
InChI key
WRQNANDWMGAFTP-UHFFFAOYSA-N
General description
Methyl acetoacetate undergoes asymmetric hydrogenation to form (R)-(-)-methyl-3-hydroxybutyrate in the presence of enantioselective Ni/SiO2 catalysts. It undergoes Pechmann reactions with phenols in various ionic liquids.
Application
Methyl acetoacetate was used in development of a simple and cost effective method for monitoring of trace formaldehyde in air. It was used to study the substrate specificity of NADPH-dependent diacetyl reductase in Escherichia coli.
Other Notes
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Danger
hcodes
Hazard Classifications
Eye Dam. 1
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter