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109533

衣康酸二甲酯

Name: 衣康酸二甲酯
Brand: ALDRICH

97%

别名:

2-(Methylene)butanedioic dimethyl ester

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关于此项目

线性分子式:

CH₃O₂CCH₂C(=CH₂)CO₂CH₃

化学文摘社编号:

617-52-7

分子量:

158.15

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24846923

EC Number:

210-519-6

Beilstein/REAXYS Number:

386674

MDL number:

MFCD00008446

Assay:

97%

Form:

solid

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属性

Quality Level

100

assay

97%

form

solid

bp

208 °C (lit.)

mp

37-41 °C (lit.)

density

1.124 g/mL at 25 °C (lit.)

functional group

ester

SMILES string

COC(=O)CC(=C)C(=O)OC

InChI

1S/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3

InChI key

ZWWQRMFIZFPUAA-UHFFFAOYSA-N

说明

General description

衣康酸二甲酯在Rh（I）催化下进行对映选择性加氢反应，在（1,2-二芳基膦基氧基）环己烷的芳环上选择适当的取代基可提高反应的活性。.

Application

衣康酸二甲酯可用于全同立构聚（丙烯）的官能化。它可用于聚酯：聚（异山梨醇衣康酸酯）和聚（异山梨醇衣康酸酯-共-琥珀酸酯）的交联。

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pictograms

GHS07

signalword

Warning

hcodes

H315,H317

pcodes

P261 - P264 - P272 - P280 - P302 + P352 - P333 + P313

Hazard Classifications

Skin Irrit. 2 - Skin Sens. 1B

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

212.0 °F - closed cup

flash_point_c

100 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

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Lot/Batch Number

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Polymers with shape memory effect from renewable resources: crosslinking of polyesters based on isosorbide, itaconic acid and succinic acid.

Goerz O and Ritter H.

Polymer International, 62(5), 709-712 (2013)

Electronic Effects in Asymmetric Catalysis: Structural Studies of Precatalysts and Intermediates in Rh-Catalyzed Hydrogenation of Dimethyl Itaconate and Acetamidocinnamic Acid Derivatives Using C(2)-Symmetric Diarylphosphinite Ligands.

T. V. RajanBabu et al.

The Journal of organic chemistry, 64(10), 3429-3447 (2001-10-25)

Enantioselectivity of Rh(I)-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives and dimethyl itaconate can be enhanced by the appropriate choice of substituents on the aromatic rings of vicinal diarylphosphinites derived from carbohydrates as well as trans-cyclohexane-1,2-diol. For example, the use of

Immune-responsive gene 1 (IRG1) and dimethyl itaconate are involved in the mussel immune response.

M Sendra et al.

Fish & shellfish immunology, 106, 645-655 (2020-08-18)

Immune-responsive gene 1 (irg1) is a gene that is well-conserved among different taxa and is highly expressed in the mussel Mytilus galloprovincialis at the constitutive level. The expression of this gene increases after a bacterial infection, primarily in haemocytes. irg1

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全球贸易项目编号

货号	GTIN
109533-100G	04061838688637
109533-500G	04061838688644