109533
衣康酸二甲酯
97%
别名:
2-(Methylene)butanedioic dimethyl ester
质量水平
方案
97%
表单
solid
沸点
208 °C (lit.)
mp
37-41 °C (lit.)
密度
1.124 g/mL at 25 °C (lit.)
官能团
ester
SMILES字符串
COC(=O)CC(=C)C(=O)OC
InChI
1S/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3
InChI key
ZWWQRMFIZFPUAA-UHFFFAOYSA-N
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一般描述
衣康酸二甲酯在Rh（I）催化下进行对映选择性加氢反应，在（1,2-二芳基膦基氧基）环己烷的芳环上选择适当的取代基可提高反应的活性。.
应用
衣康酸二甲酯可用于全同立构聚（丙烯）的官能化。它可用于聚酯：聚（异山梨醇衣康酸酯）和聚（异山梨醇衣康酸酯-共-琥珀酸酯）的交联。
警示用语：
Warning
危险声明
危险分类
Skin Irrit. 2 - Skin Sens. 1B
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
212.0 °F - closed cup
闪点(°C)
100 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
Modification of poly (propylene) through grafting with dimethyl itaconate in solution.
Yazdani-Pedram M, et al.
Macromolecular Chemistry and Physics, 199(11), 2495-2500 (1998)
M Sendra et al.
Fish & shellfish immunology, 106, 645-655 (2020-08-18)
Immune-responsive gene 1 (irg1) is a gene that is well-conserved among different taxa and is highly expressed in the mussel Mytilus galloprovincialis at the constitutive level. The expression of this gene increases after a bacterial infection, primarily in haemocytes. irg1
Polymers with shape memory effect from renewable resources: crosslinking of polyesters based on isosorbide, itaconic acid and succinic acid.
Goerz O and Ritter H.
Polymer International, 62(5), 709-712 (2013)
T. V. RajanBabu et al.
The Journal of organic chemistry, 64(10), 3429-3447 (2001-10-25)
Enantioselectivity of Rh(I)-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives and dimethyl itaconate can be enhanced by the appropriate choice of substituents on the aromatic rings of vicinal diarylphosphinites derived from carbohydrates as well as trans-cyclohexane-1,2-diol. For example, the use of
Thekla Cordes et al.
Metabolites, 11(2) (2021-03-07)
Itaconate is a small molecule metabolite that is endogenously produced by cis-aconitate decarboxylase-1 (ACOD1) in mammalian cells and influences numerous cellular processes. The metabolic consequences of itaconate in cells are diverse and contribute to its regulatory function. Here, we have
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