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109835

2-甲基吡啶

Name: 2-甲基吡啶
Brand: ALDRICH

98%

别名:

2-甲基吡啶, α-甲基吡啶, NSC 3409

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关于此项目

经验公式（希尔记法）:

C₆H₇N

化学文摘社编号:

109-06-8

分子量:

93.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24846941

EC Number:

203-643-7

Beilstein/REAXYS Number:

104581

MDL number:

MFCD00006332

Assay:

98%

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属性

vapor density

3.2 (vs air)

vapor pressure

10 mmHg ( 24.4 °C)

assay

98%

autoignition temp.

995 °F

expl. lim.

8.6 %

refractive index

n20/D 1.500 (lit.)

bp

128-129 °C (lit.)

mp

−70 °C (lit.)

solubility

H₂O: freely soluble, alcohol: miscible, diethyl ether: miscible

density

0.943 g/mL at 25 °C (lit.)

SMILES string

Cc1ccccn1

InChI

1S/C6H7N/c1-6-4-2-3-5-7-6/h2-5H,1H3

InChI key

BSKHPKMHTQYZBB-UHFFFAOYSA-N

说明

Application

2-甲基吡啶 (2-Picoline，2-Methylpyridine) 用于傅里叶变换离子回旋共振质谱研究三甲基异咯嗪的电子和质子转移反应。

2-甲基吡啶在合成途径中用于生成脱芳香化、烯丙基化和 C-H 键活化的吡啶衍生物。

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pictograms

GHS02,GHS06,GHS05

signalword

Danger

hcodes

H226,H302 + H332,H311,H314,H335

pcodes

P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1C - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

84.2 °F - closed cup

flash_point_c

29 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Calcium-mediated dearomatization, C-H bond activation, and allylation of alkylated and benzannulated pyridine derivatives.

Phillip Jochmann et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 17(43), 12115-12122 (2011-09-10)

A facile and general synthetic pathway for the production of dearomatized, allylated, and C-H bond activated pyridine derivatives is presented. Reaction of the corresponding derivative with the previously reported reagent bis(allyl)calcium, [Ca(C(3)H(5))(2)] (1), cleanly affords the product in high yield.

Stability of flavin semiquinones in the gas phase: the electron affinity, proton affinity, and hydrogen atom affinity of lumiflavin.

Tianlan Zhang et al.

The journal of physical chemistry. A, 117(44), 11136-11141 (2013-09-07)

Examination of electron transfer and proton transfer reactions of lumiflavin and proton transfer reactions of the lumiflavin radical anion by Fourier transform ion cyclotron resonance mass spectrometry is described. From the equilibrium constant determined for electron transfer between 1,4-naphthoquinone and

Influence of Proton Acceptors on the Proton-Coupled Electron Transfer Reaction Kinetics of a Ruthenium-Tyrosine Complex.

J Christian Lennox et al.

The journal of physical chemistry. B, 121(46), 10530-10542 (2017-11-14)

A polypyridyl ruthenium complex with fluorinated bipyridine ligands and a covalently bound tyrosine moiety was synthesized, and its photo-induced proton-coupled electron transfer (PCET) reactivity in acetonitrile was investigated with transient absorption spectroscopy. Using flash-quench methodology with methyl viologen as an

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全球贸易项目编号

货号	GTIN
109835-1L	04061838693068
109835-25ML	04061838693105
109835-500ML	04061838693112