110701
4,4-二甲基-1-戊烯
99%
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关于此项目
线性分子式:
CH2=CHCH2C(CH3)3
化学文摘社编号:
分子量:
98.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-101-9
Beilstein/REAXYS Number:
1731848
MDL number:
Assay:
99%
产品名称
4,4-二甲基-1-戊烯, 99%
InChI key
KLCNJIQZXOQYTE-UHFFFAOYSA-N
InChI
1S/C7H14/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3
SMILES string
CC(C)(C)CC=C
vapor pressure
231 mmHg ( 37.7 °C)
assay
99%
refractive index
n20/D 1.392 (lit.)
bp
72 °C (lit.)
density
0.683 g/mL at 25 °C (lit.)
functional group
allyl
Quality Level
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General description
4,4-Dimethyl-1-pentene is obtained by the S(N)2′ attack of the organolithium on allyl ether.
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Bailey et al.
Organic letters, 2(4), 489-491 (2000-05-18)
[reaction: see text] Allylic ethers are converted to the corresponding alcohol or phenol in virtually quantitative yield at temperatures below ambient simply by stirring a hydrocarbon solution of the ether with 1 molar equiv of tert-butyllithium. The reaction, which produces
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