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线性分子式:
C6H10(=CH2)
化学文摘社编号:
分子量:
96.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-752-4
Beilstein/REAXYS Number:
773760
MDL number:
产品名称
亚甲基环己烷, 98%
InChI key
YULMNMJFAZWLLN-UHFFFAOYSA-N
InChI
1S/C7H12/c1-7-5-3-2-4-6-7/h1-6H2
SMILES string
C=C1CCCCC1
assay
98%
form
liquid
refractive index
n20/D 1.449 (lit.)
bp
102-103 °C (lit.)
density
0.8 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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General description
亚甲基环己烷环是通过将4-戊烯基溴化镁与2-氰基-2-环烯酮进行1,4-加成,然后进行Pd(II)介导的氧化环化而获得的。 它经过气相臭氧分解形成二次有机气溶胶(SOA)。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
28.4 °F - closed cup
flash_point_c
-2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Conny Müller et al.
Electrophoresis, 28(9), 1364-1370 (2007-03-21)
The composition of secondary organic aerosol (SOA) from the gas phase ozonolysis of methylenecyclohexane was analyzed in a series of indoor aerosol chamber experiments. Capillary electrophoresis-electrospray ionization-ion trap mass spectrometry (CE/ESI-ITMS) was used for qualitative and quantitative analysis of SOA
Min-Tsang Hsieh et al.
Organic & biomolecular chemistry, 10(23), 4609-4617 (2012-05-15)
A highly efficient annulative approach towards the construction of the structurally attractive methylenecyclohexane ring was developed through a convenient 1,4-addition of 4-pentenylmagnesium bromide to 2-cyano-2-cycloalkenones followed by a Pd(II)-mediated oxidative cyclization of the resulting ω-unsaturated α-cyano ketones. Based on this
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