111279
4-戊烯-1-醇
99%
别名:
2-烯丙基乙醇
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关于此项目
线性分子式:
CH2=CH(CH2)3OH
化学文摘社编号:
分子量:
86.13
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39020310
UNSPSC Code:
12352100
EC Number:
212-473-2
MDL number:
Beilstein/REAXYS Number:
1560163
Assay:
99%
Quality Level
assay
99%
refractive index
n20/D 1.429 (lit.)
bp
134-137 °C (lit.)
density
0.834 g/mL at 25 °C (lit.)
functional group
allyl, hydroxyl
SMILES string
OCCCC=C
InChI
1S/C5H10O/c1-2-3-4-5-6/h2,6H,1,3-5H2
InChI key
LQAVWYMTUMSFBE-UHFFFAOYSA-N
General description
在溶液中，以 HATU 为偶联剂， 4-戊烯-1-醇与线性肽的 C 末端形成酯键。
Application
4-戊烯-1-醇可作为反应物，与氯磺酰异氰酸酯（142662）反应，制备氨基磺酸酯。所得衍生酯在Cu作为催化剂存在的条件下，进行对映选择性分子内氮杂环丙烷化反应。以4-戊烯-1-醇作为催化剂，碳酸氢盐为助催化剂，研究氧代-二过氧钨酸盐 (VI) 配合物对烯烃的环氧化反应。
Enantioselective Intramolecular Copper-Catalyzed Aziridination of Sulfamates
Audrey Esteoule.et al.
Synthesis, 1251-1251 (2007)
Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst.
Maiti SK, et al.
New. J. Chem., 30(3), 479-489 (2006)
Marina D Rvovic et al.
Journal of molecular modeling, 17(6), 1251-1257 (2010-08-17)
The mechanism of phenylselenoetherification of pent-4-en-1-ol using some bases (pyridine, triethylamine, quinoline, 2,2'-bipyridine) as catalyst was examined through studies of kinetics of the cyclization, by UV-VIS spectrophotometry. It was demonstrated that the intramolecular cyclization is facilitated in the presence of
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 111279-1G | 04061837864704 |
| 111279-50G | 04061838698872 |
| 111279-10G | 04061838698865 |