111996
苯基丙二酸二乙酯
98%
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线性分子式:
C6H5CH(COOC2H5)2
化学文摘社编号:
分子量:
236.26
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39024637
UNSPSC Code:
12352100
EC Number:
201-456-5
MDL number:
Beilstein/REAXYS Number:
614465
Assay:
98%
InChI key
FGYDHYCFHBSNPE-UHFFFAOYSA-N
InChI
1S/C13H16O4/c1-3-16-12(14)11(13(15)17-4-2)10-8-6-5-7-9-10/h5-9,11H,3-4H2,1-2H3
SMILES string
CCOC(=O)C(C(=O)OCC)c1ccccc1
assay
98%
refractive index
n20/D 1.491 (lit.)
bp
170-172 °C/14 mmHg (lit.)
mp
16 °C (lit.)
density
1.095 g/mL at 25 °C (lit.)
functional group
ester, phenyl
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Application
Diethyl phenylmalonate was used in the synthesis of felbamate-d4 (2-phenyl-1,3-propanediol-l,l,3,3-d4 dicarbamate) using lithium aluminum deuteride.
General description
Diethyl phenylmalonate was partially hydrolysed to the corresponding chiral monoester by various immobilized preparations of lipase from Thermomyces lanuginosa.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Partial and enantioselective hydrolysis of diethyl phenylmalonate by immobilized preparations of lipase from Thermomyces lanuginose.
Enz. Microbiol. Technol., 40(5), 1280-1285 (2007)
Synthesis of deuterium?labeled felbamate from diethyl phenylmalonate.
Choi YM, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 23(7), 785-789 (1986)
Mitali Kundu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 183, 332-338 (2017-05-02)
The aim of this present work is to make soluble DEPM in aqueous medium through the formation inclusion complex into the hydrophobic hollow space of β-cyclodextrin (β-Cyd) which will provide a novel approach for designing drug delivery system in aqueous
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