111996
苯基丙二酸二乙酯
98%
方案
98%
折射率
n20/D 1.491 (lit.)
沸点
170-172 °C/14 mmHg (lit.)
mp
16 °C (lit.)
密度
1.095 g/mL at 25 °C (lit.)
官能团
ester
phenyl
SMILES字符串
CCOC(=O)C(C(=O)OCC)c1ccccc1
InChI
1S/C13H16O4/c1-3-16-12(14)11(13(15)17-4-2)10-8-6-5-7-9-10/h5-9,11H,3-4H2,1-2H3
InChI key
FGYDHYCFHBSNPE-UHFFFAOYSA-N
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一般描述
Diethyl phenylmalonate was partially hydrolysed to the corresponding chiral monoester by various immobilized preparations of lipase from Thermomyces lanuginosa.
应用
Diethyl phenylmalonate was used in the synthesis of felbamate-d4 (2-phenyl-1,3-propanediol-l,l,3,3-d4 dicarbamate) using lithium aluminum deuteride.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Synthesis of deuterium?labeled felbamate from diethyl phenylmalonate.
Choi YM, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 23(7), 785-789 (1986)
Mitali Kundu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 183, 332-338 (2017-05-02)
The aim of this present work is to make soluble DEPM in aqueous medium through the formation inclusion complex into the hydrophobic hollow space of β-cyclodextrin (β-Cyd) which will provide a novel approach for designing drug delivery system in aqueous
Partial and enantioselective hydrolysis of diethyl phenylmalonate by immobilized preparations of lipase from Thermomyces lanuginose.
Enz. Microbiol. Technol., 40(5), 1280-1285 (2007)
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